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The crystal structures of two chalcones: (2E)-1-(5-chloro­thio­phen-2-yl)-3-(2-methyl­phen­yl)prop-2-en-1-one and (2E)-1-(anthracen-9-yl)-3-[4-(propan-2-yl)phen­yl]prop-2-en-1-one

In the crystal of compound (I), C(14)H(11)ClOS, mol­ecules are linked by C—H⋯O hydrogen bonds to form simple C(5) chains. Compound (II), C(26)H(22)O, crystallizes with Z′ = 2 in space group P-1; one of the mol­ecules is fully ordered but the other is disordered over two sets of atomic sites having o...

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Autores principales: Girisha, Marisiddaiah, Yathirajan, Hemmige S., Jasinski, Jerry P., Glidewell, Christopher
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4971861/
https://www.ncbi.nlm.nih.gov/pubmed/27536402
http://dx.doi.org/10.1107/S2056989016011592
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author Girisha, Marisiddaiah
Yathirajan, Hemmige S.
Jasinski, Jerry P.
Glidewell, Christopher
author_facet Girisha, Marisiddaiah
Yathirajan, Hemmige S.
Jasinski, Jerry P.
Glidewell, Christopher
author_sort Girisha, Marisiddaiah
collection PubMed
description In the crystal of compound (I), C(14)H(11)ClOS, mol­ecules are linked by C—H⋯O hydrogen bonds to form simple C(5) chains. Compound (II), C(26)H(22)O, crystallizes with Z′ = 2 in space group P-1; one of the mol­ecules is fully ordered but the other is disordered over two sets of atomic sites having occupancies 0.644 (3) and 0.356 (3). The two disordered components differ from one another in the orientation of the isopropyl substituents, and both differ from the ordered mol­ecules in the arrangement of the central propenone spacer unit, so that the crystal of (II) contains three distinct conformers. The ordered and disordered conformers each form a C(8) chain built from a single type of C—H⋯O hydrogen bond but those formed by the disordered conformers differ from that formed by the ordered form.
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spelling pubmed-49718612016-08-17 The crystal structures of two chalcones: (2E)-1-(5-chloro­thio­phen-2-yl)-3-(2-methyl­phen­yl)prop-2-en-1-one and (2E)-1-(anthracen-9-yl)-3-[4-(propan-2-yl)phen­yl]prop-2-en-1-one Girisha, Marisiddaiah Yathirajan, Hemmige S. Jasinski, Jerry P. Glidewell, Christopher Acta Crystallogr E Crystallogr Commun Research Communications In the crystal of compound (I), C(14)H(11)ClOS, mol­ecules are linked by C—H⋯O hydrogen bonds to form simple C(5) chains. Compound (II), C(26)H(22)O, crystallizes with Z′ = 2 in space group P-1; one of the mol­ecules is fully ordered but the other is disordered over two sets of atomic sites having occupancies 0.644 (3) and 0.356 (3). The two disordered components differ from one another in the orientation of the isopropyl substituents, and both differ from the ordered mol­ecules in the arrangement of the central propenone spacer unit, so that the crystal of (II) contains three distinct conformers. The ordered and disordered conformers each form a C(8) chain built from a single type of C—H⋯O hydrogen bond but those formed by the disordered conformers differ from that formed by the ordered form. International Union of Crystallography 2016-07-19 /pmc/articles/PMC4971861/ /pubmed/27536402 http://dx.doi.org/10.1107/S2056989016011592 Text en © Girisha et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Girisha, Marisiddaiah
Yathirajan, Hemmige S.
Jasinski, Jerry P.
Glidewell, Christopher
The crystal structures of two chalcones: (2E)-1-(5-chloro­thio­phen-2-yl)-3-(2-methyl­phen­yl)prop-2-en-1-one and (2E)-1-(anthracen-9-yl)-3-[4-(propan-2-yl)phen­yl]prop-2-en-1-one
title The crystal structures of two chalcones: (2E)-1-(5-chloro­thio­phen-2-yl)-3-(2-methyl­phen­yl)prop-2-en-1-one and (2E)-1-(anthracen-9-yl)-3-[4-(propan-2-yl)phen­yl]prop-2-en-1-one
title_full The crystal structures of two chalcones: (2E)-1-(5-chloro­thio­phen-2-yl)-3-(2-methyl­phen­yl)prop-2-en-1-one and (2E)-1-(anthracen-9-yl)-3-[4-(propan-2-yl)phen­yl]prop-2-en-1-one
title_fullStr The crystal structures of two chalcones: (2E)-1-(5-chloro­thio­phen-2-yl)-3-(2-methyl­phen­yl)prop-2-en-1-one and (2E)-1-(anthracen-9-yl)-3-[4-(propan-2-yl)phen­yl]prop-2-en-1-one
title_full_unstemmed The crystal structures of two chalcones: (2E)-1-(5-chloro­thio­phen-2-yl)-3-(2-methyl­phen­yl)prop-2-en-1-one and (2E)-1-(anthracen-9-yl)-3-[4-(propan-2-yl)phen­yl]prop-2-en-1-one
title_short The crystal structures of two chalcones: (2E)-1-(5-chloro­thio­phen-2-yl)-3-(2-methyl­phen­yl)prop-2-en-1-one and (2E)-1-(anthracen-9-yl)-3-[4-(propan-2-yl)phen­yl]prop-2-en-1-one
title_sort crystal structures of two chalcones: (2e)-1-(5-chloro­thio­phen-2-yl)-3-(2-methyl­phen­yl)prop-2-en-1-one and (2e)-1-(anthracen-9-yl)-3-[4-(propan-2-yl)phen­yl]prop-2-en-1-one
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4971861/
https://www.ncbi.nlm.nih.gov/pubmed/27536402
http://dx.doi.org/10.1107/S2056989016011592
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