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The crystal structures of two chalcones: (2E)-1-(5-chlorothiophen-2-yl)-3-(2-methylphenyl)prop-2-en-1-one and (2E)-1-(anthracen-9-yl)-3-[4-(propan-2-yl)phenyl]prop-2-en-1-one
In the crystal of compound (I), C(14)H(11)ClOS, molecules are linked by C—H⋯O hydrogen bonds to form simple C(5) chains. Compound (II), C(26)H(22)O, crystallizes with Z′ = 2 in space group P-1; one of the molecules is fully ordered but the other is disordered over two sets of atomic sites having o...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2016
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4971861/ https://www.ncbi.nlm.nih.gov/pubmed/27536402 http://dx.doi.org/10.1107/S2056989016011592 |
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author | Girisha, Marisiddaiah Yathirajan, Hemmige S. Jasinski, Jerry P. Glidewell, Christopher |
author_facet | Girisha, Marisiddaiah Yathirajan, Hemmige S. Jasinski, Jerry P. Glidewell, Christopher |
author_sort | Girisha, Marisiddaiah |
collection | PubMed |
description | In the crystal of compound (I), C(14)H(11)ClOS, molecules are linked by C—H⋯O hydrogen bonds to form simple C(5) chains. Compound (II), C(26)H(22)O, crystallizes with Z′ = 2 in space group P-1; one of the molecules is fully ordered but the other is disordered over two sets of atomic sites having occupancies 0.644 (3) and 0.356 (3). The two disordered components differ from one another in the orientation of the isopropyl substituents, and both differ from the ordered molecules in the arrangement of the central propenone spacer unit, so that the crystal of (II) contains three distinct conformers. The ordered and disordered conformers each form a C(8) chain built from a single type of C—H⋯O hydrogen bond but those formed by the disordered conformers differ from that formed by the ordered form. |
format | Online Article Text |
id | pubmed-4971861 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-49718612016-08-17 The crystal structures of two chalcones: (2E)-1-(5-chlorothiophen-2-yl)-3-(2-methylphenyl)prop-2-en-1-one and (2E)-1-(anthracen-9-yl)-3-[4-(propan-2-yl)phenyl]prop-2-en-1-one Girisha, Marisiddaiah Yathirajan, Hemmige S. Jasinski, Jerry P. Glidewell, Christopher Acta Crystallogr E Crystallogr Commun Research Communications In the crystal of compound (I), C(14)H(11)ClOS, molecules are linked by C—H⋯O hydrogen bonds to form simple C(5) chains. Compound (II), C(26)H(22)O, crystallizes with Z′ = 2 in space group P-1; one of the molecules is fully ordered but the other is disordered over two sets of atomic sites having occupancies 0.644 (3) and 0.356 (3). The two disordered components differ from one another in the orientation of the isopropyl substituents, and both differ from the ordered molecules in the arrangement of the central propenone spacer unit, so that the crystal of (II) contains three distinct conformers. The ordered and disordered conformers each form a C(8) chain built from a single type of C—H⋯O hydrogen bond but those formed by the disordered conformers differ from that formed by the ordered form. International Union of Crystallography 2016-07-19 /pmc/articles/PMC4971861/ /pubmed/27536402 http://dx.doi.org/10.1107/S2056989016011592 Text en © Girisha et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Girisha, Marisiddaiah Yathirajan, Hemmige S. Jasinski, Jerry P. Glidewell, Christopher The crystal structures of two chalcones: (2E)-1-(5-chlorothiophen-2-yl)-3-(2-methylphenyl)prop-2-en-1-one and (2E)-1-(anthracen-9-yl)-3-[4-(propan-2-yl)phenyl]prop-2-en-1-one |
title | The crystal structures of two chalcones: (2E)-1-(5-chlorothiophen-2-yl)-3-(2-methylphenyl)prop-2-en-1-one and (2E)-1-(anthracen-9-yl)-3-[4-(propan-2-yl)phenyl]prop-2-en-1-one |
title_full | The crystal structures of two chalcones: (2E)-1-(5-chlorothiophen-2-yl)-3-(2-methylphenyl)prop-2-en-1-one and (2E)-1-(anthracen-9-yl)-3-[4-(propan-2-yl)phenyl]prop-2-en-1-one |
title_fullStr | The crystal structures of two chalcones: (2E)-1-(5-chlorothiophen-2-yl)-3-(2-methylphenyl)prop-2-en-1-one and (2E)-1-(anthracen-9-yl)-3-[4-(propan-2-yl)phenyl]prop-2-en-1-one |
title_full_unstemmed | The crystal structures of two chalcones: (2E)-1-(5-chlorothiophen-2-yl)-3-(2-methylphenyl)prop-2-en-1-one and (2E)-1-(anthracen-9-yl)-3-[4-(propan-2-yl)phenyl]prop-2-en-1-one |
title_short | The crystal structures of two chalcones: (2E)-1-(5-chlorothiophen-2-yl)-3-(2-methylphenyl)prop-2-en-1-one and (2E)-1-(anthracen-9-yl)-3-[4-(propan-2-yl)phenyl]prop-2-en-1-one |
title_sort | crystal structures of two chalcones: (2e)-1-(5-chlorothiophen-2-yl)-3-(2-methylphenyl)prop-2-en-1-one and (2e)-1-(anthracen-9-yl)-3-[4-(propan-2-yl)phenyl]prop-2-en-1-one |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4971861/ https://www.ncbi.nlm.nih.gov/pubmed/27536402 http://dx.doi.org/10.1107/S2056989016011592 |
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