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11-Step Total Synthesis of (−)-Maoecrystal V
[Image: see text] An expedient, practical, and enantioselective route to the highly congested ent-kaurane diterpene maoecrystal V is presented. This route, which has been several years in the making, is loosely modeled after a key pinacol shift in the proposed biosynthesis. Only 11 steps, many of wh...
Autores principales: | Cernijenko, Artiom, Risgaard, Rune, Baran, Phil S. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2016
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4974602/ https://www.ncbi.nlm.nih.gov/pubmed/27457680 http://dx.doi.org/10.1021/jacs.6b06623 |
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