The Influence of Crown Ether and Alcohol on Unsaturation and Molar Mass of Poly(propylene oxide)s Prepared by Use of Potassium t-Butoxide: Reinvestigation of Chain Transfer Reactions

Potassium t-butoxide dissolved in tetrahydrofuran effectively initiates homogeneous polymerization of propylene oxide at room temperature. Unsaturation and molar mass (M (n)) of the polymers prepared depend on the presence of additives, such as macrocyclic ligand 18-crown-6 (L) and t-butanol. Applic...

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Detalles Bibliográficos
Autores principales: Grobelny, Zbigniew, Swinarew, Andrzej, Jurek-Suliga, Justyna, Skrzeczyna, Kinga, Gabor, Jadwiga, Łężniak, Marta
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Hindawi Publishing Corporation 2016
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4977391/
https://www.ncbi.nlm.nih.gov/pubmed/27528874
http://dx.doi.org/10.1155/2016/3727062

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