Synthesis of 2-substituted tetraphenylenes via transition-metal-catalyzed derivatization of tetraphenylene

A new strategy for the synthesis of 2-substituted tetraphenylenes through a transition-metal-catalyzed derivatization has been developed. Three types of functionalities, including OAc, X (Cl, Br, I) and carbonyl, were introduced onto tetraphenylene, which allows the easy access to a variety of monos...

Descripción completa

Detalles Bibliográficos
Autores principales: Pan, Shulei, Jiang, Hang, Zhang, Yanghui, Zhang, Yu, Chen, Dushen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4979733/
https://www.ncbi.nlm.nih.gov/pubmed/27559378
http://dx.doi.org/10.3762/bjoc.12.122
_version_ 1782447364901961728
author Pan, Shulei
Jiang, Hang
Zhang, Yanghui
Zhang, Yu
Chen, Dushen
author_facet Pan, Shulei
Jiang, Hang
Zhang, Yanghui
Zhang, Yu
Chen, Dushen
author_sort Pan, Shulei
collection PubMed
description A new strategy for the synthesis of 2-substituted tetraphenylenes through a transition-metal-catalyzed derivatization has been developed. Three types of functionalities, including OAc, X (Cl, Br, I) and carbonyl, were introduced onto tetraphenylene, which allows the easy access to a variety of monosubstituted tetraphenylenes. These reactions could accelerate research on the properties and application of tetraphenylene derivatives.
format Online
Article
Text
id pubmed-4979733
institution National Center for Biotechnology Information
language English
publishDate 2016
publisher Beilstein-Institut
record_format MEDLINE/PubMed
spelling pubmed-49797332016-08-24 Synthesis of 2-substituted tetraphenylenes via transition-metal-catalyzed derivatization of tetraphenylene Pan, Shulei Jiang, Hang Zhang, Yanghui Zhang, Yu Chen, Dushen Beilstein J Org Chem Letter A new strategy for the synthesis of 2-substituted tetraphenylenes through a transition-metal-catalyzed derivatization has been developed. Three types of functionalities, including OAc, X (Cl, Br, I) and carbonyl, were introduced onto tetraphenylene, which allows the easy access to a variety of monosubstituted tetraphenylenes. These reactions could accelerate research on the properties and application of tetraphenylene derivatives. Beilstein-Institut 2016-06-22 /pmc/articles/PMC4979733/ /pubmed/27559378 http://dx.doi.org/10.3762/bjoc.12.122 Text en Copyright © 2016, Pan et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Letter
Pan, Shulei
Jiang, Hang
Zhang, Yanghui
Zhang, Yu
Chen, Dushen
Synthesis of 2-substituted tetraphenylenes via transition-metal-catalyzed derivatization of tetraphenylene
title Synthesis of 2-substituted tetraphenylenes via transition-metal-catalyzed derivatization of tetraphenylene
title_full Synthesis of 2-substituted tetraphenylenes via transition-metal-catalyzed derivatization of tetraphenylene
title_fullStr Synthesis of 2-substituted tetraphenylenes via transition-metal-catalyzed derivatization of tetraphenylene
title_full_unstemmed Synthesis of 2-substituted tetraphenylenes via transition-metal-catalyzed derivatization of tetraphenylene
title_short Synthesis of 2-substituted tetraphenylenes via transition-metal-catalyzed derivatization of tetraphenylene
title_sort synthesis of 2-substituted tetraphenylenes via transition-metal-catalyzed derivatization of tetraphenylene
topic Letter
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4979733/
https://www.ncbi.nlm.nih.gov/pubmed/27559378
http://dx.doi.org/10.3762/bjoc.12.122
work_keys_str_mv AT panshulei synthesisof2substitutedtetraphenylenesviatransitionmetalcatalyzedderivatizationoftetraphenylene
AT jianghang synthesisof2substitutedtetraphenylenesviatransitionmetalcatalyzedderivatizationoftetraphenylene
AT zhangyanghui synthesisof2substitutedtetraphenylenesviatransitionmetalcatalyzedderivatizationoftetraphenylene
AT zhangyu synthesisof2substitutedtetraphenylenesviatransitionmetalcatalyzedderivatizationoftetraphenylene
AT chendushen synthesisof2substitutedtetraphenylenesviatransitionmetalcatalyzedderivatizationoftetraphenylene

Ejemplares similares