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TMSBr-mediated solvent- and work-up-free synthesis of α-2-deoxyglycosides from glycals

The thio-additions of glycals were efficiently promoted by a stoichiometric amount of trimethylsilyl bromide (TMSBr) to produce S-2-deoxyglycosides under solvent-free conditions in good to excellent yields. In addition, with triphenylphosphine oxide as an additive, the TMSBr-mediated direct glycosyl...

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Detalles Bibliográficos
Autores principales:	Hsu, Mei-Yuan, Liu, Yi-Pei, Lam, Sarah, Lin, Su-Ching, Wang, Cheng-Chung
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2016
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4979735/ https://www.ncbi.nlm.nih.gov/pubmed/27559420 http://dx.doi.org/10.3762/bjoc.12.164

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