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Reactivity studies of pincer bis-protic N-heterocyclic carbene complexes of platinum and palladium under basic conditions

Bis-protic N-heterocyclic carbene complexes of platinum and palladium (4) yield dimeric structures 6 when treated with sodium tert-butoxide in CH(2)Cl(2). The use of a more polar solvent (THF) and a strong base (LiN(iPr)(2)) gave the lithium chloride adducts monobasic complex 7 or analogous dibasic...

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Detalles Bibliográficos
Autores principales:	Marelius, David C, Moore, Curtis E, Rheingold, Arnold L, Grotjahn, Douglas B
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2016
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4979752/ https://www.ncbi.nlm.nih.gov/pubmed/27559382 http://dx.doi.org/10.3762/bjoc.12.126

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