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NeoPHOX – a structurally tunable ligand system for asymmetric catalysis
A synthesis of new NeoPHOX ligands derived from serine or threonine has been developed. The central intermediate is a NeoPHOX derivative bearing a methoxycarbonyl group at the stereogenic center next to the oxazoline N atom. The addition of methylmagnesium chloride leads to a tertiary alcohol, which...
Autores principales: | Padevět, Jaroslav, Schrems, Marcus G, Scheil, Robin, Pfaltz, Andreas |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4979954/ https://www.ncbi.nlm.nih.gov/pubmed/27559370 http://dx.doi.org/10.3762/bjoc.12.114 |
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