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Octahedral Tin Dioxide Nanocrystals Anchored on Vertically Aligned Carbon Aerogels as High Capacity Anode Materials for Lithium-Ion Batteries
A novel binder-free graphene - carbon nanotubes - SnO(2) (GCNT-SnO(2)) aerogel with vertically aligned pores was prepared via a simple and efficient directional freezing method. SnO(2) octahedrons exposed of {221} high energy facets were uniformly distributed and tightly anchored on multidimensional...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4980600/ https://www.ncbi.nlm.nih.gov/pubmed/27510357 http://dx.doi.org/10.1038/srep31496 |
Sumario: | A novel binder-free graphene - carbon nanotubes - SnO(2) (GCNT-SnO(2)) aerogel with vertically aligned pores was prepared via a simple and efficient directional freezing method. SnO(2) octahedrons exposed of {221} high energy facets were uniformly distributed and tightly anchored on multidimensional graphene/carbon nanotube (GCNT) composites. Vertically aligned pores can effectively prevent the emersion of “closed” pores which cannot load the active SnO(2) nanoparticles, further ensure quick immersion of electrolyte throughout the aerogel, and can largely shorten the transport distance between lithium ions and active sites of SnO(2). Especially, excellent electrical conductivity of GCNT-SnO(2) aerogel was achieved as a result of good interconnected networks of graphene and CNTs. Furthermore, meso- and macroporous structures with large surface area created by the vertically aligned pores can provide great benefit to the favorable transport kinetics for both lithium ion and electrons and afford sufficient space for volume expansion of SnO(2). Due to the well-designed architecture of GCNT-SnO(2) aerogel, a high specific capacity of 1190 mAh/g with good long-term cycling stability up to 1000 times was achieved. This work provides a promising strategy for preparing free-standing and binder-free active electrode materials with high performance for lithium ion batteries and other energy storage devices. |
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