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Synthesis of Trimeric Organozinc Compounds and their Subsequent Reaction with Oxygen

A conventional solution‐based route to a cyclic trimeric organozinc compound [{Zn(Et)(β‐diketonate)}(3)] (β‐diketonate=OC(OMe)CHC(Me)O, 1) is described, with 1 structurally characterized for the first time. The ligand selection of bidentate β‐diketonates is shown to be key to isolating a cyclic trim...

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Detalles Bibliográficos
Autores principales: Manzi, Joe A., Knapp, Caroline E., Parkin, Ivan P., Carmalt, Claire J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4981048/
https://www.ncbi.nlm.nih.gov/pubmed/27547637
http://dx.doi.org/10.1002/open.201600040