A Ferrocenyl‐Backboned Unsymmetric O,C‐Coordinating Ligand and Its Tin Derivatives

The syntheses of the phosphonyl‐substituted ferrocenyl stannane Fe[{η (5)‐C(5)H(3)‐1‐SnPh(3)‐2‐P(O)(O‐iPr)(2)}{η (5)‐C(5)H(4)P(O)(O‐iPr)(2)}] (1) and its iodine derivative Fe[{η (5)‐C(5)H(3)‐1‐SnPh(2)I‐2‐P(O)(O‐iPr)(2)}{η (5)‐C(5)H(4)P(O)(O‐iPr)(2)}] (2) are reported. The syntheses of the correspond...

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Detalles Bibliográficos
Autores principales: Janssen, Bastian, Lutter, Michael, Alnasr, Hazem, Krossing, Ingo, Jurkschat, Klaus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4981052/
https://www.ncbi.nlm.nih.gov/pubmed/27547641
http://dx.doi.org/10.1002/open.201600048
Descripción
Sumario:The syntheses of the phosphonyl‐substituted ferrocenyl stannane Fe[{η (5)‐C(5)H(3)‐1‐SnPh(3)‐2‐P(O)(O‐iPr)(2)}{η (5)‐C(5)H(4)P(O)(O‐iPr)(2)}] (1) and its iodine derivative Fe[{η (5)‐C(5)H(3)‐1‐SnPh(2)I‐2‐P(O)(O‐iPr)(2)}{η (5)‐C(5)H(4)P(O)(O‐iPr)(2)}] (2) are reported. The syntheses of the corresponding salts Fe[{η (5)‐C(5)H(3)‐1‐SnPh(2)‐2‐P(O)(O‐iPr)(2)}{η (5)‐C(5)H(4)P(O)(O‐iPr)(2)}]X (3, X=Al{OC(CF(3))(3)}(4), 4, X=ClO(4), 5, X=HgI(3)), respectively, are also described. The compounds are characterized by elemental analyses, (1)H, (13)C, (31)P, (119)Sn NMR and IR spectroscopy, electrospray ionization mass spectrometry, and, except for 4 and 5, single‐crystal X‐ray diffraction analyses.

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