A Ferrocenyl‐Backboned Unsymmetric O,C‐Coordinating Ligand and Its Tin Derivatives

The syntheses of the phosphonyl‐substituted ferrocenyl stannane Fe[{η (5)‐C(5)H(3)‐1‐SnPh(3)‐2‐P(O)(O‐iPr)(2)}{η (5)‐C(5)H(4)P(O)(O‐iPr)(2)}] (1) and its iodine derivative Fe[{η (5)‐C(5)H(3)‐1‐SnPh(2)I‐2‐P(O)(O‐iPr)(2)}{η (5)‐C(5)H(4)P(O)(O‐iPr)(2)}] (2) are reported. The syntheses of the correspond...

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Autores principales: Janssen, Bastian, Lutter, Michael, Alnasr, Hazem, Krossing, Ingo, Jurkschat, Klaus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4981052/
https://www.ncbi.nlm.nih.gov/pubmed/27547641
http://dx.doi.org/10.1002/open.201600048
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author Janssen, Bastian
Lutter, Michael
Alnasr, Hazem
Krossing, Ingo
Jurkschat, Klaus
author_facet Janssen, Bastian
Lutter, Michael
Alnasr, Hazem
Krossing, Ingo
Jurkschat, Klaus
author_sort Janssen, Bastian
collection PubMed
description The syntheses of the phosphonyl‐substituted ferrocenyl stannane Fe[{η (5)‐C(5)H(3)‐1‐SnPh(3)‐2‐P(O)(O‐iPr)(2)}{η (5)‐C(5)H(4)P(O)(O‐iPr)(2)}] (1) and its iodine derivative Fe[{η (5)‐C(5)H(3)‐1‐SnPh(2)I‐2‐P(O)(O‐iPr)(2)}{η (5)‐C(5)H(4)P(O)(O‐iPr)(2)}] (2) are reported. The syntheses of the corresponding salts Fe[{η (5)‐C(5)H(3)‐1‐SnPh(2)‐2‐P(O)(O‐iPr)(2)}{η (5)‐C(5)H(4)P(O)(O‐iPr)(2)}]X (3, X=Al{OC(CF(3))(3)}(4), 4, X=ClO(4), 5, X=HgI(3)), respectively, are also described. The compounds are characterized by elemental analyses, (1)H, (13)C, (31)P, (119)Sn NMR and IR spectroscopy, electrospray ionization mass spectrometry, and, except for 4 and 5, single‐crystal X‐ray diffraction analyses.
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spelling pubmed-49810522016-08-19 A Ferrocenyl‐Backboned Unsymmetric O,C‐Coordinating Ligand and Its Tin Derivatives Janssen, Bastian Lutter, Michael Alnasr, Hazem Krossing, Ingo Jurkschat, Klaus ChemistryOpen Full Papers The syntheses of the phosphonyl‐substituted ferrocenyl stannane Fe[{η (5)‐C(5)H(3)‐1‐SnPh(3)‐2‐P(O)(O‐iPr)(2)}{η (5)‐C(5)H(4)P(O)(O‐iPr)(2)}] (1) and its iodine derivative Fe[{η (5)‐C(5)H(3)‐1‐SnPh(2)I‐2‐P(O)(O‐iPr)(2)}{η (5)‐C(5)H(4)P(O)(O‐iPr)(2)}] (2) are reported. The syntheses of the corresponding salts Fe[{η (5)‐C(5)H(3)‐1‐SnPh(2)‐2‐P(O)(O‐iPr)(2)}{η (5)‐C(5)H(4)P(O)(O‐iPr)(2)}]X (3, X=Al{OC(CF(3))(3)}(4), 4, X=ClO(4), 5, X=HgI(3)), respectively, are also described. The compounds are characterized by elemental analyses, (1)H, (13)C, (31)P, (119)Sn NMR and IR spectroscopy, electrospray ionization mass spectrometry, and, except for 4 and 5, single‐crystal X‐ray diffraction analyses. John Wiley and Sons Inc. 2016-06-15 /pmc/articles/PMC4981052/ /pubmed/27547641 http://dx.doi.org/10.1002/open.201600048 Text en © 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial (http://creativecommons.org/licenses/by-nc/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Full Papers
Janssen, Bastian
Lutter, Michael
Alnasr, Hazem
Krossing, Ingo
Jurkschat, Klaus
A Ferrocenyl‐Backboned Unsymmetric O,C‐Coordinating Ligand and Its Tin Derivatives
title A Ferrocenyl‐Backboned Unsymmetric O,C‐Coordinating Ligand and Its Tin Derivatives
title_full A Ferrocenyl‐Backboned Unsymmetric O,C‐Coordinating Ligand and Its Tin Derivatives
title_fullStr A Ferrocenyl‐Backboned Unsymmetric O,C‐Coordinating Ligand and Its Tin Derivatives
title_full_unstemmed A Ferrocenyl‐Backboned Unsymmetric O,C‐Coordinating Ligand and Its Tin Derivatives
title_short A Ferrocenyl‐Backboned Unsymmetric O,C‐Coordinating Ligand and Its Tin Derivatives
title_sort ferrocenyl‐backboned unsymmetric o,c‐coordinating ligand and its tin derivatives
topic Full Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4981052/
https://www.ncbi.nlm.nih.gov/pubmed/27547641
http://dx.doi.org/10.1002/open.201600048
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