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Synthesis and Alkali‐Metal‐Ion Complexation of P‐Stereogenic Diphosphacrowns
Phosphine is conformationally stable because of the high inversion energy barrier of the phosphorus atom, which allows the phosphorus atom to become a chiral center. Thus, enantiopure P‐stereogenic 12‐, 15‐, 18‐, and 21‐membered aliphatic phosphines “diphosphacrowns” were synthesized from secondary...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4981053/ https://www.ncbi.nlm.nih.gov/pubmed/27547642 http://dx.doi.org/10.1002/open.201600033 |