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Alkali Metal Cation versus Proton and Methyl Cation Affinities: Structure and Bonding Mechanism
We have analyzed the structure and bonding of gas‐phase Cl−X and [HCl−X](+) complexes for X(+)= H(+), CH(3) (+), Li(+), and Na(+), using relativistic density functional theory (DFT). We wish to establish a quantitative trend in affinities of the anionic and neutral Lewis bases Cl(−) and HCl for the...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4984409/ https://www.ncbi.nlm.nih.gov/pubmed/27551660 http://dx.doi.org/10.1002/open.201500208 |