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Systematic Studies on 3 d‐ and 4 f‐Metal Containing Polyoxometalates Suitable for Organic Derivatization

Premium polyoxometalates! The organic functionalization of 3 d‐metalsubstituted polyoxometalates and the synthesis of new metal‐oxo clusters with accessible 3 d‐ and 4 f‐metal centers suitable for organic derivatization are discussed in this thesis. A total number of 39 compounds were structurally c...

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Detalles Bibliográficos
Autor principal: Artetxe, Beñat
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4984411/
https://www.ncbi.nlm.nih.gov/pubmed/27551662
http://dx.doi.org/10.1002/open.201500221
Descripción
Sumario:Premium polyoxometalates! The organic functionalization of 3 d‐metalsubstituted polyoxometalates and the synthesis of new metal‐oxo clusters with accessible 3 d‐ and 4 f‐metal centers suitable for organic derivatization are discussed in this thesis. A total number of 39 compounds were structurally characterized, and their luminescent and magnetic properties analyzed. The solution behavior was studied by NMR spectroscopy, mass spectrometry, and light‐scattering techniques.[Image: see text]