Crystal structure of hexa­kis­(dimethyl sulfoxide-κO)manganese(II) diiodide

The asymmetric unit of the title salt, [Mn(C(2)H(6)OS)(6)]I(2), consists of one Mn(II) ion, six O-bound dimethyl sulfoxide (DMSO) ligands and two I(−) counter-anions. The isolated complex cations have an octa­hedral configuration and are grouped in hexa­gonally arranged rows extending parallel to [1...

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Detalles Bibliográficos
Autores principales: Glatz, Mathias, Schroffenegger, Martina, Weil, Matthias, Kirchner, Karl
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992903/
https://www.ncbi.nlm.nih.gov/pubmed/27555928
http://dx.doi.org/10.1107/S2056989016008896
Descripción
Sumario:The asymmetric unit of the title salt, [Mn(C(2)H(6)OS)(6)]I(2), consists of one Mn(II) ion, six O-bound dimethyl sulfoxide (DMSO) ligands and two I(−) counter-anions. The isolated complex cations have an octa­hedral configuration and are grouped in hexa­gonally arranged rows extending parallel to [100]. The two I(−) anions are located between the rows and are linked to the cations through two weak C—H⋯I inter­actions.

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