Crystal structure of hexa­kis­(dimethyl sulfoxide-κO)manganese(II) diiodide

The asymmetric unit of the title salt, [Mn(C(2)H(6)OS)(6)]I(2), consists of one Mn(II) ion, six O-bound dimethyl sulfoxide (DMSO) ligands and two I(−) counter-anions. The isolated complex cations have an octa­hedral configuration and are grouped in hexa­gonally arranged rows extending parallel to [1...

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Autores principales: Glatz, Mathias, Schroffenegger, Martina, Weil, Matthias, Kirchner, Karl
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992903/
https://www.ncbi.nlm.nih.gov/pubmed/27555928
http://dx.doi.org/10.1107/S2056989016008896
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author Glatz, Mathias
Schroffenegger, Martina
Weil, Matthias
Kirchner, Karl
author_facet Glatz, Mathias
Schroffenegger, Martina
Weil, Matthias
Kirchner, Karl
author_sort Glatz, Mathias
collection PubMed
description The asymmetric unit of the title salt, [Mn(C(2)H(6)OS)(6)]I(2), consists of one Mn(II) ion, six O-bound dimethyl sulfoxide (DMSO) ligands and two I(−) counter-anions. The isolated complex cations have an octa­hedral configuration and are grouped in hexa­gonally arranged rows extending parallel to [100]. The two I(−) anions are located between the rows and are linked to the cations through two weak C—H⋯I inter­actions.
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spelling pubmed-49929032016-08-23 Crystal structure of hexa­kis­(dimethyl sulfoxide-κO)manganese(II) diiodide Glatz, Mathias Schroffenegger, Martina Weil, Matthias Kirchner, Karl Acta Crystallogr E Crystallogr Commun Research Communications The asymmetric unit of the title salt, [Mn(C(2)H(6)OS)(6)]I(2), consists of one Mn(II) ion, six O-bound dimethyl sulfoxide (DMSO) ligands and two I(−) counter-anions. The isolated complex cations have an octa­hedral configuration and are grouped in hexa­gonally arranged rows extending parallel to [100]. The two I(−) anions are located between the rows and are linked to the cations through two weak C—H⋯I inter­actions. International Union of Crystallography 2016-06-10 /pmc/articles/PMC4992903/ /pubmed/27555928 http://dx.doi.org/10.1107/S2056989016008896 Text en © Glatz et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Glatz, Mathias
Schroffenegger, Martina
Weil, Matthias
Kirchner, Karl
Crystal structure of hexa­kis­(dimethyl sulfoxide-κO)manganese(II) diiodide
title Crystal structure of hexa­kis­(dimethyl sulfoxide-κO)manganese(II) diiodide
title_full Crystal structure of hexa­kis­(dimethyl sulfoxide-κO)manganese(II) diiodide
title_fullStr Crystal structure of hexa­kis­(dimethyl sulfoxide-κO)manganese(II) diiodide
title_full_unstemmed Crystal structure of hexa­kis­(dimethyl sulfoxide-κO)manganese(II) diiodide
title_short Crystal structure of hexa­kis­(dimethyl sulfoxide-κO)manganese(II) diiodide
title_sort crystal structure of hexa­kis­(dimethyl sulfoxide-κo)manganese(ii) diiodide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992903/
https://www.ncbi.nlm.nih.gov/pubmed/27555928
http://dx.doi.org/10.1107/S2056989016008896
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