Crystal structure of bis­(isonicotinamide-κN (1))bis­(thio­cyanato-κN)zinc

The asymmetric unit of the title complex, [Zn(SCN)(2)(C(6)H(6)N(2)O)(2)], consists of one Zn(2+) cation located on a twofold rotation axis, as well as of one thio­cyanate anion and one neutral isonicotinamide ligand, both occupying general positions. The Zn(2+) cation is tetra­hedrally coordinated i...

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Detalles Bibliográficos
Autores principales: Neumann, Tristan, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992907/
https://www.ncbi.nlm.nih.gov/pubmed/27555932
http://dx.doi.org/10.1107/S2056989016008963
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author Neumann, Tristan
Jess, Inke
Näther, Christian
author_facet Neumann, Tristan
Jess, Inke
Näther, Christian
author_sort Neumann, Tristan
collection PubMed
description The asymmetric unit of the title complex, [Zn(SCN)(2)(C(6)H(6)N(2)O)(2)], consists of one Zn(2+) cation located on a twofold rotation axis, as well as of one thio­cyanate anion and one neutral isonicotinamide ligand, both occupying general positions. The Zn(2+) cation is tetra­hedrally coordinated into a discrete complex by the N atoms of two symmetry-related thio­cyanate anions and by the pyridine N atoms of two isonicotinamide ligands. The complexes are linked by inter­molecular C—H⋯O and N—H⋯O, and weak inter­molecular N—H⋯S hydrogen-bonding inter­actions into a three-dimensional network.
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spelling pubmed-49929072016-08-23 Crystal structure of bis­(isonicotinamide-κN (1))bis­(thio­cyanato-κN)zinc Neumann, Tristan Jess, Inke Näther, Christian Acta Crystallogr E Crystallogr Commun Research Communications The asymmetric unit of the title complex, [Zn(SCN)(2)(C(6)H(6)N(2)O)(2)], consists of one Zn(2+) cation located on a twofold rotation axis, as well as of one thio­cyanate anion and one neutral isonicotinamide ligand, both occupying general positions. The Zn(2+) cation is tetra­hedrally coordinated into a discrete complex by the N atoms of two symmetry-related thio­cyanate anions and by the pyridine N atoms of two isonicotinamide ligands. The complexes are linked by inter­molecular C—H⋯O and N—H⋯O, and weak inter­molecular N—H⋯S hydrogen-bonding inter­actions into a three-dimensional network. International Union of Crystallography 2016-06-10 /pmc/articles/PMC4992907/ /pubmed/27555932 http://dx.doi.org/10.1107/S2056989016008963 Text en © Neumann et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Neumann, Tristan
Jess, Inke
Näther, Christian
Crystal structure of bis­(isonicotinamide-κN (1))bis­(thio­cyanato-κN)zinc
title Crystal structure of bis­(isonicotinamide-κN (1))bis­(thio­cyanato-κN)zinc
title_full Crystal structure of bis­(isonicotinamide-κN (1))bis­(thio­cyanato-κN)zinc
title_fullStr Crystal structure of bis­(isonicotinamide-κN (1))bis­(thio­cyanato-κN)zinc
title_full_unstemmed Crystal structure of bis­(isonicotinamide-κN (1))bis­(thio­cyanato-κN)zinc
title_short Crystal structure of bis­(isonicotinamide-κN (1))bis­(thio­cyanato-κN)zinc
title_sort crystal structure of bis­(isonicotinamide-κn (1))bis­(thio­cyanato-κn)zinc
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992907/
https://www.ncbi.nlm.nih.gov/pubmed/27555932
http://dx.doi.org/10.1107/S2056989016008963
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