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Crystal structure of 2-(4-acetylanilino)-2-oxoethyl 3-(4-hydroxyphenyl)propionate
In the title compound, C(19)H(19)NO(5), the amide carbonyl O atom is positioned anti to the other two carbonyl O atoms. The 4-hydroxyhydrocinnamate fragment is disordered over two positions with an occupancy ratio of 0.729 (12):0.271 (12). The N—(C=O)—C plane of the acetamide group and the acetat...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992909/ https://www.ncbi.nlm.nih.gov/pubmed/27555934 http://dx.doi.org/10.1107/S205698901600894X |
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author | Ashraf, Zaman Kim, Daeyoung Seo, Sung-Yum Kang, Sung Kwon |
author_facet | Ashraf, Zaman Kim, Daeyoung Seo, Sung-Yum Kang, Sung Kwon |
author_sort | Ashraf, Zaman |
collection | PubMed |
description | In the title compound, C(19)H(19)NO(5), the amide carbonyl O atom is positioned anti to the other two carbonyl O atoms. The 4-hydroxyhydrocinnamate fragment is disordered over two positions with an occupancy ratio of 0.729 (12):0.271 (12). The N—(C=O)—C plane of the acetamide group and the acetate O—(C=O)—C plane are almost co-planar; the acetamide plane makes dihedral angles of 1.9 (6) and 16.0 (19)°, respectively, with the acetate planes of the major and minor occupancy components. In the crystal, N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds link the molecules into a supramolecular sheet structure parallel to (102). |
format | Online Article Text |
id | pubmed-4992909 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-49929092016-08-23 Crystal structure of 2-(4-acetylanilino)-2-oxoethyl 3-(4-hydroxyphenyl)propionate Ashraf, Zaman Kim, Daeyoung Seo, Sung-Yum Kang, Sung Kwon Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(19)H(19)NO(5), the amide carbonyl O atom is positioned anti to the other two carbonyl O atoms. The 4-hydroxyhydrocinnamate fragment is disordered over two positions with an occupancy ratio of 0.729 (12):0.271 (12). The N—(C=O)—C plane of the acetamide group and the acetate O—(C=O)—C plane are almost co-planar; the acetamide plane makes dihedral angles of 1.9 (6) and 16.0 (19)°, respectively, with the acetate planes of the major and minor occupancy components. In the crystal, N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds link the molecules into a supramolecular sheet structure parallel to (102). International Union of Crystallography 2016-06-10 /pmc/articles/PMC4992909/ /pubmed/27555934 http://dx.doi.org/10.1107/S205698901600894X Text en © Ashraf et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Ashraf, Zaman Kim, Daeyoung Seo, Sung-Yum Kang, Sung Kwon Crystal structure of 2-(4-acetylanilino)-2-oxoethyl 3-(4-hydroxyphenyl)propionate |
title | Crystal structure of 2-(4-acetylanilino)-2-oxoethyl 3-(4-hydroxyphenyl)propionate |
title_full | Crystal structure of 2-(4-acetylanilino)-2-oxoethyl 3-(4-hydroxyphenyl)propionate |
title_fullStr | Crystal structure of 2-(4-acetylanilino)-2-oxoethyl 3-(4-hydroxyphenyl)propionate |
title_full_unstemmed | Crystal structure of 2-(4-acetylanilino)-2-oxoethyl 3-(4-hydroxyphenyl)propionate |
title_short | Crystal structure of 2-(4-acetylanilino)-2-oxoethyl 3-(4-hydroxyphenyl)propionate |
title_sort | crystal structure of 2-(4-acetylanilino)-2-oxoethyl 3-(4-hydroxyphenyl)propionate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992909/ https://www.ncbi.nlm.nih.gov/pubmed/27555934 http://dx.doi.org/10.1107/S205698901600894X |
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