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Crystal structure of 2-(4-acetyl­anilino)-2-oxoethyl 3-(4-hy­droxy­phen­yl)propionate

In the title compound, C(19)H(19)NO(5), the amide carbonyl O atom is positioned anti to the other two carbonyl O atoms. The 4-hy­droxy­hydro­cinnamate fragment is disordered over two positions with an occupancy ratio of 0.729 (12):0.271 (12). The N—(C=O)—C plane of the acetamide group and the acetat...

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Detalles Bibliográficos
Autores principales: Ashraf, Zaman, Kim, Daeyoung, Seo, Sung-Yum, Kang, Sung Kwon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992909/
https://www.ncbi.nlm.nih.gov/pubmed/27555934
http://dx.doi.org/10.1107/S205698901600894X
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author Ashraf, Zaman
Kim, Daeyoung
Seo, Sung-Yum
Kang, Sung Kwon
author_facet Ashraf, Zaman
Kim, Daeyoung
Seo, Sung-Yum
Kang, Sung Kwon
author_sort Ashraf, Zaman
collection PubMed
description In the title compound, C(19)H(19)NO(5), the amide carbonyl O atom is positioned anti to the other two carbonyl O atoms. The 4-hy­droxy­hydro­cinnamate fragment is disordered over two positions with an occupancy ratio of 0.729 (12):0.271 (12). The N—(C=O)—C plane of the acetamide group and the acetate O—(C=O)—C plane are almost co-planar; the acetamide plane makes dihedral angles of 1.9 (6) and 16.0 (19)°, respectively, with the acetate planes of the major and minor occupancy components. In the crystal, N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a supra­molecular sheet structure parallel to (102).
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spelling pubmed-49929092016-08-23 Crystal structure of 2-(4-acetyl­anilino)-2-oxoethyl 3-(4-hy­droxy­phen­yl)propionate Ashraf, Zaman Kim, Daeyoung Seo, Sung-Yum Kang, Sung Kwon Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(19)H(19)NO(5), the amide carbonyl O atom is positioned anti to the other two carbonyl O atoms. The 4-hy­droxy­hydro­cinnamate fragment is disordered over two positions with an occupancy ratio of 0.729 (12):0.271 (12). The N—(C=O)—C plane of the acetamide group and the acetate O—(C=O)—C plane are almost co-planar; the acetamide plane makes dihedral angles of 1.9 (6) and 16.0 (19)°, respectively, with the acetate planes of the major and minor occupancy components. In the crystal, N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a supra­molecular sheet structure parallel to (102). International Union of Crystallography 2016-06-10 /pmc/articles/PMC4992909/ /pubmed/27555934 http://dx.doi.org/10.1107/S205698901600894X Text en © Ashraf et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Ashraf, Zaman
Kim, Daeyoung
Seo, Sung-Yum
Kang, Sung Kwon
Crystal structure of 2-(4-acetyl­anilino)-2-oxoethyl 3-(4-hy­droxy­phen­yl)propionate
title Crystal structure of 2-(4-acetyl­anilino)-2-oxoethyl 3-(4-hy­droxy­phen­yl)propionate
title_full Crystal structure of 2-(4-acetyl­anilino)-2-oxoethyl 3-(4-hy­droxy­phen­yl)propionate
title_fullStr Crystal structure of 2-(4-acetyl­anilino)-2-oxoethyl 3-(4-hy­droxy­phen­yl)propionate
title_full_unstemmed Crystal structure of 2-(4-acetyl­anilino)-2-oxoethyl 3-(4-hy­droxy­phen­yl)propionate
title_short Crystal structure of 2-(4-acetyl­anilino)-2-oxoethyl 3-(4-hy­droxy­phen­yl)propionate
title_sort crystal structure of 2-(4-acetyl­anilino)-2-oxoethyl 3-(4-hy­droxy­phen­yl)propionate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992909/
https://www.ncbi.nlm.nih.gov/pubmed/27555934
http://dx.doi.org/10.1107/S205698901600894X
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