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Crystal structure of dimethyl 3,4,5,6-tetraphenylcyclohexa-3,5-diene-1,2-dicarboxylate
In the title compound, C(34)H(28)O(4), the cyclohexadiene ring has a screw-boat conformation with a torsion angle between the double bonds being on average ca 15° [15.2 (3) and −15.3 (3) in the two independent molecules]. All four phenyl rings in both molecules are arranged in a propeller-like c...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992912/ https://www.ncbi.nlm.nih.gov/pubmed/27555937 http://dx.doi.org/10.1107/S2056989016009403 |
Sumario: | In the title compound, C(34)H(28)O(4), the cyclohexadiene ring has a screw-boat conformation with a torsion angle between the double bonds being on average ca 15° [15.2 (3) and −15.3 (3) in the two independent molecules]. All four phenyl rings in both molecules are arranged in a propeller-like conformation. The two molecules exhibit S,R- and R,S- chirality, respectively, and are connected via C—H⋯O intermolecular interactions. In turn, these weakly bound dimers form the molecular crystal. |
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