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Crystal structure of dimethyl 3,4,5,6-tetra­phenyl­cyclo­hexa-3,5-diene-1,2-di­carboxyl­ate

In the title compound, C(34)H(28)O(4), the cyclo­hexa­diene ring has a screw-boat conformation with a torsion angle between the double bonds being on average ca 15° [15.2 (3) and −15.3 (3) in the two independent mol­ecules]. All four phenyl rings in both mol­ecules are arranged in a propeller-like c...

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Detalles Bibliográficos
Autores principales: Greenberg, Fred H., Nazarenko, Alexander Y.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992912/
https://www.ncbi.nlm.nih.gov/pubmed/27555937
http://dx.doi.org/10.1107/S2056989016009403
Descripción
Sumario:In the title compound, C(34)H(28)O(4), the cyclo­hexa­diene ring has a screw-boat conformation with a torsion angle between the double bonds being on average ca 15° [15.2 (3) and −15.3 (3) in the two independent mol­ecules]. All four phenyl rings in both mol­ecules are arranged in a propeller-like conformation. The two mol­ecules exhibit S,R- and R,S- chirality, respectively, and are connected via C—H⋯O inter­molecular inter­actions. In turn, these weakly bound dimers form the mol­ecular crystal.