Crystal structure of racemic [(1R,2S,3R,4S,6S)-2,6-bis­(furan-2-yl)-4-hy­droxy-4-(thio­phen-2-yl)cyclo­hexane-1,3-di­yl]bis­(thio­phen-2-yl­methanone)

In the title compound, C(28)H(22)O(5)S(3), the central cyclo­hexane ring adopts a chair conformation. The atoms of the furan ring attached to the 6-position of the central cyclo­hexane ring are disordered over two sets of sites with occupancies of 0.832 (5) and 0.168 (5). The hy­droxy group is disor...

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Autores principales: Çelik, Ísmail, Ersanlı, Cem Cüneyt, Akkurt, Mehmet, Gezegen, Hayrettin, Köseoğlu, Rahmi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992919/
https://www.ncbi.nlm.nih.gov/pubmed/27555944
http://dx.doi.org/10.1107/S2056989016009452
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author Çelik, Ísmail
Ersanlı, Cem Cüneyt
Akkurt, Mehmet
Gezegen, Hayrettin
Köseoğlu, Rahmi
author_facet Çelik, Ísmail
Ersanlı, Cem Cüneyt
Akkurt, Mehmet
Gezegen, Hayrettin
Köseoğlu, Rahmi
author_sort Çelik, Ísmail
collection PubMed
description In the title compound, C(28)H(22)O(5)S(3), the central cyclo­hexane ring adopts a chair conformation. The atoms of the furan ring attached to the 6-position of the central cyclo­hexane ring are disordered over two sets of sites with occupancies of 0.832 (5) and 0.168 (5). The hy­droxy group is disordered over two positions (at the 4- and 6-positions of the cyclo­hexane ring) in the ratio 0.832 (5):0.168 (5). In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds and C—H⋯π inter­actions, forming layers parallel to (100).
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spelling pubmed-49929192016-08-23 Crystal structure of racemic [(1R,2S,3R,4S,6S)-2,6-bis­(furan-2-yl)-4-hy­droxy-4-(thio­phen-2-yl)cyclo­hexane-1,3-di­yl]bis­(thio­phen-2-yl­methanone) Çelik, Ísmail Ersanlı, Cem Cüneyt Akkurt, Mehmet Gezegen, Hayrettin Köseoğlu, Rahmi Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(28)H(22)O(5)S(3), the central cyclo­hexane ring adopts a chair conformation. The atoms of the furan ring attached to the 6-position of the central cyclo­hexane ring are disordered over two sets of sites with occupancies of 0.832 (5) and 0.168 (5). The hy­droxy group is disordered over two positions (at the 4- and 6-positions of the cyclo­hexane ring) in the ratio 0.832 (5):0.168 (5). In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds and C—H⋯π inter­actions, forming layers parallel to (100). International Union of Crystallography 2016-06-17 /pmc/articles/PMC4992919/ /pubmed/27555944 http://dx.doi.org/10.1107/S2056989016009452 Text en © Çelik et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Çelik, Ísmail
Ersanlı, Cem Cüneyt
Akkurt, Mehmet
Gezegen, Hayrettin
Köseoğlu, Rahmi
Crystal structure of racemic [(1R,2S,3R,4S,6S)-2,6-bis­(furan-2-yl)-4-hy­droxy-4-(thio­phen-2-yl)cyclo­hexane-1,3-di­yl]bis­(thio­phen-2-yl­methanone)
title Crystal structure of racemic [(1R,2S,3R,4S,6S)-2,6-bis­(furan-2-yl)-4-hy­droxy-4-(thio­phen-2-yl)cyclo­hexane-1,3-di­yl]bis­(thio­phen-2-yl­methanone)
title_full Crystal structure of racemic [(1R,2S,3R,4S,6S)-2,6-bis­(furan-2-yl)-4-hy­droxy-4-(thio­phen-2-yl)cyclo­hexane-1,3-di­yl]bis­(thio­phen-2-yl­methanone)
title_fullStr Crystal structure of racemic [(1R,2S,3R,4S,6S)-2,6-bis­(furan-2-yl)-4-hy­droxy-4-(thio­phen-2-yl)cyclo­hexane-1,3-di­yl]bis­(thio­phen-2-yl­methanone)
title_full_unstemmed Crystal structure of racemic [(1R,2S,3R,4S,6S)-2,6-bis­(furan-2-yl)-4-hy­droxy-4-(thio­phen-2-yl)cyclo­hexane-1,3-di­yl]bis­(thio­phen-2-yl­methanone)
title_short Crystal structure of racemic [(1R,2S,3R,4S,6S)-2,6-bis­(furan-2-yl)-4-hy­droxy-4-(thio­phen-2-yl)cyclo­hexane-1,3-di­yl]bis­(thio­phen-2-yl­methanone)
title_sort crystal structure of racemic [(1r,2s,3r,4s,6s)-2,6-bis­(furan-2-yl)-4-hy­droxy-4-(thio­phen-2-yl)cyclo­hexane-1,3-di­yl]bis­(thio­phen-2-yl­methanone)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992919/
https://www.ncbi.nlm.nih.gov/pubmed/27555944
http://dx.doi.org/10.1107/S2056989016009452
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