Crystal structure of chlorido­[trans-1-(di­phenyl­phosphane­thioyl-κS)-2-(di­phenyl­phosphano­yl)ethene]gold(I) di­chloro­methane hemisolvate

The title compound, [AuCl(C(26)H(22)OP(2)S)]·0.5CH(2)Cl(2), crystallizes with a trans-O—P⋯P—S geometry of the groups either side of the C=C double bond, which prevents any intra­molecular contact between the Au and O atoms. The Au(I) atom exhibits a nearly linear coordination [Cl—Au—S = 177.55 (4)°]...

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Detalles Bibliográficos
Autores principales: Taouss, Christina, Jones, Peter G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992926/
https://www.ncbi.nlm.nih.gov/pubmed/27555951
http://dx.doi.org/10.1107/S2056989016009816
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author Taouss, Christina
Jones, Peter G.
author_facet Taouss, Christina
Jones, Peter G.
author_sort Taouss, Christina
collection PubMed
description The title compound, [AuCl(C(26)H(22)OP(2)S)]·0.5CH(2)Cl(2), crystallizes with a trans-O—P⋯P—S geometry of the groups either side of the C=C double bond, which prevents any intra­molecular contact between the Au and O atoms. The Au(I) atom exhibits a nearly linear coordination [Cl—Au—S = 177.55 (4)°]. The mol­ecules associate to form broad ribbons parallel to the c axis via two C—H⋯O, one C—H⋯Cl(Au) and one Au⋯Cl inter­action.
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spelling pubmed-49929262016-08-23 Crystal structure of chlorido­[trans-1-(di­phenyl­phosphane­thioyl-κS)-2-(di­phenyl­phosphano­yl)ethene]gold(I) di­chloro­methane hemisolvate Taouss, Christina Jones, Peter G. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [AuCl(C(26)H(22)OP(2)S)]·0.5CH(2)Cl(2), crystallizes with a trans-O—P⋯P—S geometry of the groups either side of the C=C double bond, which prevents any intra­molecular contact between the Au and O atoms. The Au(I) atom exhibits a nearly linear coordination [Cl—Au—S = 177.55 (4)°]. The mol­ecules associate to form broad ribbons parallel to the c axis via two C—H⋯O, one C—H⋯Cl(Au) and one Au⋯Cl inter­action. International Union of Crystallography 2016-06-21 /pmc/articles/PMC4992926/ /pubmed/27555951 http://dx.doi.org/10.1107/S2056989016009816 Text en © Taouss and Jones 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Taouss, Christina
Jones, Peter G.
Crystal structure of chlorido­[trans-1-(di­phenyl­phosphane­thioyl-κS)-2-(di­phenyl­phosphano­yl)ethene]gold(I) di­chloro­methane hemisolvate
title Crystal structure of chlorido­[trans-1-(di­phenyl­phosphane­thioyl-κS)-2-(di­phenyl­phosphano­yl)ethene]gold(I) di­chloro­methane hemisolvate
title_full Crystal structure of chlorido­[trans-1-(di­phenyl­phosphane­thioyl-κS)-2-(di­phenyl­phosphano­yl)ethene]gold(I) di­chloro­methane hemisolvate
title_fullStr Crystal structure of chlorido­[trans-1-(di­phenyl­phosphane­thioyl-κS)-2-(di­phenyl­phosphano­yl)ethene]gold(I) di­chloro­methane hemisolvate
title_full_unstemmed Crystal structure of chlorido­[trans-1-(di­phenyl­phosphane­thioyl-κS)-2-(di­phenyl­phosphano­yl)ethene]gold(I) di­chloro­methane hemisolvate
title_short Crystal structure of chlorido­[trans-1-(di­phenyl­phosphane­thioyl-κS)-2-(di­phenyl­phosphano­yl)ethene]gold(I) di­chloro­methane hemisolvate
title_sort crystal structure of chlorido­[trans-1-(di­phenyl­phosphane­thioyl-κs)-2-(di­phenyl­phosphano­yl)ethene]gold(i) di­chloro­methane hemisolvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992926/
https://www.ncbi.nlm.nih.gov/pubmed/27555951
http://dx.doi.org/10.1107/S2056989016009816
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