Crystal structure of chlorido­[trans-1-(di­phenyl­phosphane­thioyl-κS)-2-(di­phenyl­phosphano­yl)ethene]gold(I) di­chloro­methane hemisolvate

The title compound, [AuCl(C(26)H(22)OP(2)S)]·0.5CH(2)Cl(2), crystallizes with a trans-O—P⋯P—S geometry of the groups either side of the C=C double bond, which prevents any intra­molecular contact between the Au and O atoms. The Au(I) atom exhibits a nearly linear coordination [Cl—Au—S = 177.55 (4)°]...

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Detalles Bibliográficos
Autores principales: Taouss, Christina, Jones, Peter G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992926/
https://www.ncbi.nlm.nih.gov/pubmed/27555951
http://dx.doi.org/10.1107/S2056989016009816

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992926/
https://www.ncbi.nlm.nih.gov/pubmed/27555951
http://dx.doi.org/10.1107/S2056989016009816

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