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Crystal structure of chlorido[trans-1-(diphenylphosphanethioyl-κS)-2-(diphenylphosphanoyl)ethene]gold(I) dichloromethane hemisolvate
The title compound, [AuCl(C(26)H(22)OP(2)S)]·0.5CH(2)Cl(2), crystallizes with a trans-O—P⋯P—S geometry of the groups either side of the C=C double bond, which prevents any intramolecular contact between the Au and O atoms. The Au(I) atom exhibits a nearly linear coordination [Cl—Au—S = 177.55 (4)°]...
Autores principales: | Taouss, Christina, Jones, Peter G. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992926/ https://www.ncbi.nlm.nih.gov/pubmed/27555951 http://dx.doi.org/10.1107/S2056989016009816 |
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