Synthesis and crystal structure of [2,7,12-trimethyl-3,7,11,17-tetra­aza­bicyclo­[11.3.1]hepta­deca-1(17),13,15-triene-κ(4) N]copper(II) bis­(perchlorate)

The title copper(II) complex of a pyridine-containing macrocycle (PyMAC), [Cu(C(16)H(28)N(4))](ClO(4))(2), has been prepared. The crystal structure reveals the Cu(II) atom to be octahedrally coordinated by a tetradentate aminopyridine macrocyclic ligand surrounding the metal cation in a square-plana...

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Autores principales: Hilvano, Edward Gabrielle V., Yang, Guang, Emnacen, Inno A., Rybak-Akimova, Elena V., Billones, Junie B., Carrillo, Maria Constancia O., Noll, Bruce C., Organo, Voltaire G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992927/
https://www.ncbi.nlm.nih.gov/pubmed/27555952
http://dx.doi.org/10.1107/S2056989016009701
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author Hilvano, Edward Gabrielle V.
Yang, Guang
Emnacen, Inno A.
Rybak-Akimova, Elena V.
Billones, Junie B.
Carrillo, Maria Constancia O.
Noll, Bruce C.
Organo, Voltaire G.
author_facet Hilvano, Edward Gabrielle V.
Yang, Guang
Emnacen, Inno A.
Rybak-Akimova, Elena V.
Billones, Junie B.
Carrillo, Maria Constancia O.
Noll, Bruce C.
Organo, Voltaire G.
author_sort Hilvano, Edward Gabrielle V.
collection PubMed
description The title copper(II) complex of a pyridine-containing macrocycle (PyMAC), [Cu(C(16)H(28)N(4))](ClO(4))(2), has been prepared. The crystal structure reveals the Cu(II) atom to be octahedrally coordinated by a tetradentate aminopyridine macrocyclic ligand surrounding the metal cation in a square-planar geometry. Two weakly bound perchlorate counter-ions occupy the axial sites above and below the macrocyclic plane. The crystal studied was refined as a two-component pseudo-merohedral twin; the refined fractional contribution of the minor component is 38.77 (8)%
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spelling pubmed-49929272016-08-23 Synthesis and crystal structure of [2,7,12-trimethyl-3,7,11,17-tetra­aza­bicyclo­[11.3.1]hepta­deca-1(17),13,15-triene-κ(4) N]copper(II) bis­(perchlorate) Hilvano, Edward Gabrielle V. Yang, Guang Emnacen, Inno A. Rybak-Akimova, Elena V. Billones, Junie B. Carrillo, Maria Constancia O. Noll, Bruce C. Organo, Voltaire G. Acta Crystallogr E Crystallogr Commun Research Communications The title copper(II) complex of a pyridine-containing macrocycle (PyMAC), [Cu(C(16)H(28)N(4))](ClO(4))(2), has been prepared. The crystal structure reveals the Cu(II) atom to be octahedrally coordinated by a tetradentate aminopyridine macrocyclic ligand surrounding the metal cation in a square-planar geometry. Two weakly bound perchlorate counter-ions occupy the axial sites above and below the macrocyclic plane. The crystal studied was refined as a two-component pseudo-merohedral twin; the refined fractional contribution of the minor component is 38.77 (8)% International Union of Crystallography 2016-06-21 /pmc/articles/PMC4992927/ /pubmed/27555952 http://dx.doi.org/10.1107/S2056989016009701 Text en © Hilvano et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Hilvano, Edward Gabrielle V.
Yang, Guang
Emnacen, Inno A.
Rybak-Akimova, Elena V.
Billones, Junie B.
Carrillo, Maria Constancia O.
Noll, Bruce C.
Organo, Voltaire G.
Synthesis and crystal structure of [2,7,12-trimethyl-3,7,11,17-tetra­aza­bicyclo­[11.3.1]hepta­deca-1(17),13,15-triene-κ(4) N]copper(II) bis­(perchlorate)
title Synthesis and crystal structure of [2,7,12-trimethyl-3,7,11,17-tetra­aza­bicyclo­[11.3.1]hepta­deca-1(17),13,15-triene-κ(4) N]copper(II) bis­(perchlorate)
title_full Synthesis and crystal structure of [2,7,12-trimethyl-3,7,11,17-tetra­aza­bicyclo­[11.3.1]hepta­deca-1(17),13,15-triene-κ(4) N]copper(II) bis­(perchlorate)
title_fullStr Synthesis and crystal structure of [2,7,12-trimethyl-3,7,11,17-tetra­aza­bicyclo­[11.3.1]hepta­deca-1(17),13,15-triene-κ(4) N]copper(II) bis­(perchlorate)
title_full_unstemmed Synthesis and crystal structure of [2,7,12-trimethyl-3,7,11,17-tetra­aza­bicyclo­[11.3.1]hepta­deca-1(17),13,15-triene-κ(4) N]copper(II) bis­(perchlorate)
title_short Synthesis and crystal structure of [2,7,12-trimethyl-3,7,11,17-tetra­aza­bicyclo­[11.3.1]hepta­deca-1(17),13,15-triene-κ(4) N]copper(II) bis­(perchlorate)
title_sort synthesis and crystal structure of [2,7,12-trimethyl-3,7,11,17-tetra­aza­bicyclo­[11.3.1]hepta­deca-1(17),13,15-triene-κ(4) n]copper(ii) bis­(perchlorate)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992927/
https://www.ncbi.nlm.nih.gov/pubmed/27555952
http://dx.doi.org/10.1107/S2056989016009701
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