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Crystal structure of bis(N,N,N′,N′-tetramethylguanidinium) tetrachloridocuprate(II)
In the structure of the title salt, (C(5)H(14)N(3))(2)[CuCl(4)], the Cu(II) atom in the anion lies on a twofold rotation axis. The tetrachloridocuprate(II) anion adopts a flattened tetrahedral coordination environment and interacts electrostatically with the tetramethylguanidinium cation. The...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992935/ https://www.ncbi.nlm.nih.gov/pubmed/27555960 http://dx.doi.org/10.1107/S2056989016010161 |
| _version_ | 1782449084771074048 |
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| author | Ndiaye, Mamadou Samb, Abdoulaye Diop, Libasse Maris, Thierry |
| author_facet | Ndiaye, Mamadou Samb, Abdoulaye Diop, Libasse Maris, Thierry |
| author_sort | Ndiaye, Mamadou |
| collection | PubMed |
| description | In the structure of the title salt, (C(5)H(14)N(3))(2)[CuCl(4)], the Cu(II) atom in the anion lies on a twofold rotation axis. The tetrachloridocuprate(II) anion adopts a flattened tetrahedral coordination environment and interacts electrostatically with the tetramethylguanidinium cation. The crystal packing is additionally consolidated through N—H⋯Cl and C—H⋯Cl hydrogen bonds, resulting in a three-dimensional network structure. |
| format | Online Article Text |
| id | pubmed-4992935 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2016 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-49929352016-08-23 Crystal structure of bis(N,N,N′,N′-tetramethylguanidinium) tetrachloridocuprate(II) Ndiaye, Mamadou Samb, Abdoulaye Diop, Libasse Maris, Thierry Acta Crystallogr E Crystallogr Commun Research Communications In the structure of the title salt, (C(5)H(14)N(3))(2)[CuCl(4)], the Cu(II) atom in the anion lies on a twofold rotation axis. The tetrachloridocuprate(II) anion adopts a flattened tetrahedral coordination environment and interacts electrostatically with the tetramethylguanidinium cation. The crystal packing is additionally consolidated through N—H⋯Cl and C—H⋯Cl hydrogen bonds, resulting in a three-dimensional network structure. International Union of Crystallography 2016-06-24 /pmc/articles/PMC4992935/ /pubmed/27555960 http://dx.doi.org/10.1107/S2056989016010161 Text en © Ndiaye et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Ndiaye, Mamadou Samb, Abdoulaye Diop, Libasse Maris, Thierry Crystal structure of bis(N,N,N′,N′-tetramethylguanidinium) tetrachloridocuprate(II) |
| title | Crystal structure of bis(N,N,N′,N′-tetramethylguanidinium) tetrachloridocuprate(II) |
| title_full | Crystal structure of bis(N,N,N′,N′-tetramethylguanidinium) tetrachloridocuprate(II) |
| title_fullStr | Crystal structure of bis(N,N,N′,N′-tetramethylguanidinium) tetrachloridocuprate(II) |
| title_full_unstemmed | Crystal structure of bis(N,N,N′,N′-tetramethylguanidinium) tetrachloridocuprate(II) |
| title_short | Crystal structure of bis(N,N,N′,N′-tetramethylguanidinium) tetrachloridocuprate(II) |
| title_sort | crystal structure of bis(n,n,n′,n′-tetramethylguanidinium) tetrachloridocuprate(ii) |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992935/ https://www.ncbi.nlm.nih.gov/pubmed/27555960 http://dx.doi.org/10.1107/S2056989016010161 |
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