Two polymorphs of trans-[3-(3-nitro­phen­yl)oxiran-2-yl](phen­yl)methanone

The title compound, C(15)H(11)NO(4), crystallizes in two polymorphic forms, centrosymmetric monoclinic and chiral ortho­rhom­bic. The geometry of the mol­ecules in the two polymorphs is slightly different, possibly due to inter­molecular inter­actions. There are no classical hydrogen bonding in thes...

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Detalles Bibliográficos
Autores principales: Greenberg, Fred H., Nazarenko, Alexander Y.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992937/
https://www.ncbi.nlm.nih.gov/pubmed/27555962
http://dx.doi.org/10.1107/S2056989016010239
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author Greenberg, Fred H.
Nazarenko, Alexander Y.
author_facet Greenberg, Fred H.
Nazarenko, Alexander Y.
author_sort Greenberg, Fred H.
collection PubMed
description The title compound, C(15)H(11)NO(4), crystallizes in two polymorphic forms, centrosymmetric monoclinic and chiral ortho­rhom­bic. The geometry of the mol­ecules in the two polymorphs is slightly different, possibly due to inter­molecular inter­actions. There are no classical hydrogen bonding in these two structures. However, a number of C—H⋯O inter­molecular inter­actions, involving both O atoms of the nitro as well the benzoyl groups, stabilize the crystal structures.
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spelling pubmed-49929372016-08-23 Two polymorphs of trans-[3-(3-nitro­phen­yl)oxiran-2-yl](phen­yl)methanone Greenberg, Fred H. Nazarenko, Alexander Y. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(15)H(11)NO(4), crystallizes in two polymorphic forms, centrosymmetric monoclinic and chiral ortho­rhom­bic. The geometry of the mol­ecules in the two polymorphs is slightly different, possibly due to inter­molecular inter­actions. There are no classical hydrogen bonding in these two structures. However, a number of C—H⋯O inter­molecular inter­actions, involving both O atoms of the nitro as well the benzoyl groups, stabilize the crystal structures. International Union of Crystallography 2016-06-28 /pmc/articles/PMC4992937/ /pubmed/27555962 http://dx.doi.org/10.1107/S2056989016010239 Text en © Greenberg and Nazarenko 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Greenberg, Fred H.
Nazarenko, Alexander Y.
Two polymorphs of trans-[3-(3-nitro­phen­yl)oxiran-2-yl](phen­yl)methanone
title Two polymorphs of trans-[3-(3-nitro­phen­yl)oxiran-2-yl](phen­yl)methanone
title_full Two polymorphs of trans-[3-(3-nitro­phen­yl)oxiran-2-yl](phen­yl)methanone
title_fullStr Two polymorphs of trans-[3-(3-nitro­phen­yl)oxiran-2-yl](phen­yl)methanone
title_full_unstemmed Two polymorphs of trans-[3-(3-nitro­phen­yl)oxiran-2-yl](phen­yl)methanone
title_short Two polymorphs of trans-[3-(3-nitro­phen­yl)oxiran-2-yl](phen­yl)methanone
title_sort two polymorphs of trans-[3-(3-nitro­phen­yl)oxiran-2-yl](phen­yl)methanone
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4992937/
https://www.ncbi.nlm.nih.gov/pubmed/27555962
http://dx.doi.org/10.1107/S2056989016010239
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