Phenol Derivatives as Coupling Partners with Alkylsilicates in Photoredox/Nickel Dual Catalysis

[Image: see text] Photoredox/nickel dual catalysis via single electron transmetalation allows coupling of C(sp(3))–C(sp(2)) hybridized centers under mild conditions. A procedure for the coupling of electron-deficient aryl triflates, -tosylates, and -mesylates with alkylbis(catecholato)silicates is p...

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Autores principales: Patel, Niki R., Molander, Gary A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4994714/
https://www.ncbi.nlm.nih.gov/pubmed/27258090
http://dx.doi.org/10.1021/acs.joc.6b00800
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author Patel, Niki R.
Molander, Gary A.
author_facet Patel, Niki R.
Molander, Gary A.
author_sort Patel, Niki R.
collection PubMed
description [Image: see text] Photoredox/nickel dual catalysis via single electron transmetalation allows coupling of C(sp(3))–C(sp(2)) hybridized centers under mild conditions. A procedure for the coupling of electron-deficient aryl triflates, -tosylates, and -mesylates with alkylbis(catecholato)silicates is presented. This method represents the first example of the use of phenol derivatives as electrophilic coupling partners in photoredox/nickel dual catalysis.
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spelling pubmed-49947142017-06-03 Phenol Derivatives as Coupling Partners with Alkylsilicates in Photoredox/Nickel Dual Catalysis Patel, Niki R. Molander, Gary A. J Org Chem [Image: see text] Photoredox/nickel dual catalysis via single electron transmetalation allows coupling of C(sp(3))–C(sp(2)) hybridized centers under mild conditions. A procedure for the coupling of electron-deficient aryl triflates, -tosylates, and -mesylates with alkylbis(catecholato)silicates is presented. This method represents the first example of the use of phenol derivatives as electrophilic coupling partners in photoredox/nickel dual catalysis. American Chemical Society 2016-06-03 2016-08-19 /pmc/articles/PMC4994714/ /pubmed/27258090 http://dx.doi.org/10.1021/acs.joc.6b00800 Text en Copyright © 2016 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Patel, Niki R.
Molander, Gary A.
Phenol Derivatives as Coupling Partners with Alkylsilicates in Photoredox/Nickel Dual Catalysis
title Phenol Derivatives as Coupling Partners with Alkylsilicates in Photoredox/Nickel Dual Catalysis
title_full Phenol Derivatives as Coupling Partners with Alkylsilicates in Photoredox/Nickel Dual Catalysis
title_fullStr Phenol Derivatives as Coupling Partners with Alkylsilicates in Photoredox/Nickel Dual Catalysis
title_full_unstemmed Phenol Derivatives as Coupling Partners with Alkylsilicates in Photoredox/Nickel Dual Catalysis
title_short Phenol Derivatives as Coupling Partners with Alkylsilicates in Photoredox/Nickel Dual Catalysis
title_sort phenol derivatives as coupling partners with alkylsilicates in photoredox/nickel dual catalysis
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4994714/
https://www.ncbi.nlm.nih.gov/pubmed/27258090
http://dx.doi.org/10.1021/acs.joc.6b00800
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AT molandergarya phenolderivativesascouplingpartnerswithalkylsilicatesinphotoredoxnickeldualcatalysis

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