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Hybrid α-Fe(2)O(3)@Ni(OH)(2) nanosheet composite for high-rate-performance supercapacitor electrode

In this study, we report a facile fabrication of ultrathin two-dimensional (2D) nanosheet hybrid composite, α-Fe(2)O(3) nanosheet@Ni(OH)(2) nanosheet, by a two-step hydrothermal method to achieve high specific capacitance and good stability performance at high charging/discharging rates when serving...

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Detalles Bibliográficos
Autores principales: Jiang, Hong, Ma, Haifeng, Jin, Ying, Wang, Lanfang, Gao, Feng, Lu, Qingyi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4995458/
https://www.ncbi.nlm.nih.gov/pubmed/27553663
http://dx.doi.org/10.1038/srep31751
Descripción
Sumario:In this study, we report a facile fabrication of ultrathin two-dimensional (2D) nanosheet hybrid composite, α-Fe(2)O(3) nanosheet@Ni(OH)(2) nanosheet, by a two-step hydrothermal method to achieve high specific capacitance and good stability performance at high charging/discharging rates when serving as electrode material of supercapacitors. The α-Fe(2)O(3)@Ni(OH)(2) hybrid electrode not only has a smooth decrease of the specific capacitance with increasing current density, compared with the sharp decline of single component of Ni(OH)(2) electrode, but also presents excellent rate capability with a specific capacitance of 356 F/g at a current density of 16 A/g and excellent cycling stability (a capacity retention of 93.3% after 500 cycles), which are superior to the performances of Ni(OH)(2) with a lower specific capacitance of 132 F/g and a lower capacity retention of 81.8% at 16 A/g. The results indicate such hybrid structure would be promising as excellent electrode material for good performances at high current densities in the future.