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Novel facile method for obtaining CdSe/polyaniline/C(60) composite materials
This study presents a novel method for the oxidative polymerization of aniline (ANI) by employing fullerene C(60)/cadmium selenide (CdSe) quantum dots, as promoting agent of the polymerization system. The polymerization initiation mechanism is based on the difference between the HOMO-LUMO energy lev...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5004180/ https://www.ncbi.nlm.nih.gov/pubmed/27572228 http://dx.doi.org/10.1038/srep32237 |
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author | Rusen, Edina Diacon, Aurel Mocanu, Alexandra Nistor, Leona Cristina |
author_facet | Rusen, Edina Diacon, Aurel Mocanu, Alexandra Nistor, Leona Cristina |
author_sort | Rusen, Edina |
collection | PubMed |
description | This study presents a novel method for the oxidative polymerization of aniline (ANI) by employing fullerene C(60)/cadmium selenide (CdSe) quantum dots, as promoting agent of the polymerization system. The polymerization initiation mechanism is based on the difference between the HOMO-LUMO energy levels of the components which permits the formation of a continuous donor-acceptor exchange. Both the polymerization reaction evolution and the molecular weights of the obtained polymers have been characterized. The novelty of the paper consists in the synthesis of a novel nano-composite material through a novel polymerization technique. The resulting material containing PANI, CdSe quantum dots and C(60) has been characterized by UV-Vis, NIR, fluorescence, TEM and GPC analyses. |
format | Online Article Text |
id | pubmed-5004180 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | Nature Publishing Group |
record_format | MEDLINE/PubMed |
spelling | pubmed-50041802016-09-07 Novel facile method for obtaining CdSe/polyaniline/C(60) composite materials Rusen, Edina Diacon, Aurel Mocanu, Alexandra Nistor, Leona Cristina Sci Rep Article This study presents a novel method for the oxidative polymerization of aniline (ANI) by employing fullerene C(60)/cadmium selenide (CdSe) quantum dots, as promoting agent of the polymerization system. The polymerization initiation mechanism is based on the difference between the HOMO-LUMO energy levels of the components which permits the formation of a continuous donor-acceptor exchange. Both the polymerization reaction evolution and the molecular weights of the obtained polymers have been characterized. The novelty of the paper consists in the synthesis of a novel nano-composite material through a novel polymerization technique. The resulting material containing PANI, CdSe quantum dots and C(60) has been characterized by UV-Vis, NIR, fluorescence, TEM and GPC analyses. Nature Publishing Group 2016-08-30 /pmc/articles/PMC5004180/ /pubmed/27572228 http://dx.doi.org/10.1038/srep32237 Text en Copyright © 2016, The Author(s) http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Article Rusen, Edina Diacon, Aurel Mocanu, Alexandra Nistor, Leona Cristina Novel facile method for obtaining CdSe/polyaniline/C(60) composite materials |
title | Novel facile method for obtaining CdSe/polyaniline/C(60) composite materials |
title_full | Novel facile method for obtaining CdSe/polyaniline/C(60) composite materials |
title_fullStr | Novel facile method for obtaining CdSe/polyaniline/C(60) composite materials |
title_full_unstemmed | Novel facile method for obtaining CdSe/polyaniline/C(60) composite materials |
title_short | Novel facile method for obtaining CdSe/polyaniline/C(60) composite materials |
title_sort | novel facile method for obtaining cdse/polyaniline/c(60) composite materials |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5004180/ https://www.ncbi.nlm.nih.gov/pubmed/27572228 http://dx.doi.org/10.1038/srep32237 |
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