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Novel facile method for obtaining CdSe/polyaniline/C(60) composite materials

This study presents a novel method for the oxidative polymerization of aniline (ANI) by employing fullerene C(60)/cadmium selenide (CdSe) quantum dots, as promoting agent of the polymerization system. The polymerization initiation mechanism is based on the difference between the HOMO-LUMO energy lev...

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Detalles Bibliográficos
Autores principales: Rusen, Edina, Diacon, Aurel, Mocanu, Alexandra, Nistor, Leona Cristina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5004180/
https://www.ncbi.nlm.nih.gov/pubmed/27572228
http://dx.doi.org/10.1038/srep32237
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author Rusen, Edina
Diacon, Aurel
Mocanu, Alexandra
Nistor, Leona Cristina
author_facet Rusen, Edina
Diacon, Aurel
Mocanu, Alexandra
Nistor, Leona Cristina
author_sort Rusen, Edina
collection PubMed
description This study presents a novel method for the oxidative polymerization of aniline (ANI) by employing fullerene C(60)/cadmium selenide (CdSe) quantum dots, as promoting agent of the polymerization system. The polymerization initiation mechanism is based on the difference between the HOMO-LUMO energy levels of the components which permits the formation of a continuous donor-acceptor exchange. Both the polymerization reaction evolution and the molecular weights of the obtained polymers have been characterized. The novelty of the paper consists in the synthesis of a novel nano-composite material through a novel polymerization technique. The resulting material containing PANI, CdSe quantum dots and C(60) has been characterized by UV-Vis, NIR, fluorescence, TEM and GPC analyses.
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spelling pubmed-50041802016-09-07 Novel facile method for obtaining CdSe/polyaniline/C(60) composite materials Rusen, Edina Diacon, Aurel Mocanu, Alexandra Nistor, Leona Cristina Sci Rep Article This study presents a novel method for the oxidative polymerization of aniline (ANI) by employing fullerene C(60)/cadmium selenide (CdSe) quantum dots, as promoting agent of the polymerization system. The polymerization initiation mechanism is based on the difference between the HOMO-LUMO energy levels of the components which permits the formation of a continuous donor-acceptor exchange. Both the polymerization reaction evolution and the molecular weights of the obtained polymers have been characterized. The novelty of the paper consists in the synthesis of a novel nano-composite material through a novel polymerization technique. The resulting material containing PANI, CdSe quantum dots and C(60) has been characterized by UV-Vis, NIR, fluorescence, TEM and GPC analyses. Nature Publishing Group 2016-08-30 /pmc/articles/PMC5004180/ /pubmed/27572228 http://dx.doi.org/10.1038/srep32237 Text en Copyright © 2016, The Author(s) http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
spellingShingle Article
Rusen, Edina
Diacon, Aurel
Mocanu, Alexandra
Nistor, Leona Cristina
Novel facile method for obtaining CdSe/polyaniline/C(60) composite materials
title Novel facile method for obtaining CdSe/polyaniline/C(60) composite materials
title_full Novel facile method for obtaining CdSe/polyaniline/C(60) composite materials
title_fullStr Novel facile method for obtaining CdSe/polyaniline/C(60) composite materials
title_full_unstemmed Novel facile method for obtaining CdSe/polyaniline/C(60) composite materials
title_short Novel facile method for obtaining CdSe/polyaniline/C(60) composite materials
title_sort novel facile method for obtaining cdse/polyaniline/c(60) composite materials
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5004180/
https://www.ncbi.nlm.nih.gov/pubmed/27572228
http://dx.doi.org/10.1038/srep32237
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