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1000-fold enhancement in proton conductivity of a MOF using post-synthetically anchored proton transporters
Pyridinol, a coordinating zwitter-ionic species serves as stoichiometrically loadable and non-leachable proton carrier. The partial replacement of the pyridinol by stronger hydrogen bonding, coordinating guest, ethylene glycol (EG), offers 1000-fold enhancement in conductivity (10(−6) to 10(−3) Scm(...
Autores principales: | Shalini, Sorout, Dhavale, Vishal M., Eldho, Kavalakal M., Kurungot, Sreekumar, Ajithkumar, Thallaseril G., Vaidhyanathan, Ramanathan |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5006155/ https://www.ncbi.nlm.nih.gov/pubmed/27577681 http://dx.doi.org/10.1038/srep32489 |
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