Diverse N‐Heterocyclic Ring Systems via Aza‐Heck Cyclizations of N‐(Pentafluorobenzoyloxy)sulfonamides

Aza‐Heck cyclizations initiated by oxidative addition of Pd(0)‐catalysts into the N−O bond of N‐(pentafluoro‐benzoyloxy)sulfonamides are described. These studies, which encompass only the second class of aza‐Heck reaction developed to date, provide direct access to diverse N‐heterocyclic ring system...

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Detalles Bibliográficos
Autores principales: Hazelden, Ian R., Ma, Xiaofeng, Langer, Thomas, Bower, John F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5010782/
https://www.ncbi.nlm.nih.gov/pubmed/27460965
http://dx.doi.org/10.1002/anie.201605152
Descripción
Sumario:Aza‐Heck cyclizations initiated by oxidative addition of Pd(0)‐catalysts into the N−O bond of N‐(pentafluoro‐benzoyloxy)sulfonamides are described. These studies, which encompass only the second class of aza‐Heck reaction developed to date, provide direct access to diverse N‐heterocyclic ring systems.

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