CO Gas Sensing Properties of Pure and Cu-Incorporated SnO(2) Nanoparticles: A Study of Cu-Induced Modifications

Pure and copper (Cu)-incorporated tin oxide (SnO(2)) pellet gas sensors with characteristics provoking gas sensitivity were fabricated and used for measuring carbon monoxide (CO) atmospheres. Non-spherical pure SnO(2) nano-structures were prepared by using urea as the precipitation agent. The resultant SnO(2) powders were ball milled and incorporated with a transition metal, Cu, via chemical synthesis method. The incorporation is confirmed by high-resolution transmission electron microscope (HRTEM) analysis. By utilizing Cu-incorporated SnO(2) pellets an increase in the CO sensitivity by an order of three, and a decrease in the response and recovery times by an order of two, were obtained. This improvement in the sensitivity is due to two factors that arise due to Cu incorporation: necks between the microparticles and stacking faults in the grains. These two factors increased the conductivity and oxygen adsorption, respectively, at the pellets’ surface of SnO(2) which, in turn, raised the CO sensitivity.