Cargando…
Superfluorinated Ionic Liquid Crystals Based on Supramolecular, Halogen‐Bonded Anions
Unconventional ionic liquid crystals in which the liquid crystallinity is enabled by halogen‐bonded supramolecular anions [C(n)F(2 n+1)‐I⋅⋅⋅I⋅⋅⋅I‐C(n)F(2 n+1)](−) are reported. The material system is unique in many ways, demonstrating for the first time 1) ionic, halogen‐bonded liquid crystals, and...
Autores principales: | , , , , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2016
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5021112/ https://www.ncbi.nlm.nih.gov/pubmed/27073033 http://dx.doi.org/10.1002/anie.201601278 |
_version_ | 1782453302227632128 |
---|---|
author | Cavallo, Gabriella Terraneo, Giancarlo Monfredini, Alessandro Saccone, Marco Priimagi, Arri Pilati, Tullio Resnati, Giuseppe Metrangolo, Pierangelo Bruce, Duncan W. |
author_facet | Cavallo, Gabriella Terraneo, Giancarlo Monfredini, Alessandro Saccone, Marco Priimagi, Arri Pilati, Tullio Resnati, Giuseppe Metrangolo, Pierangelo Bruce, Duncan W. |
author_sort | Cavallo, Gabriella |
collection | PubMed |
description | Unconventional ionic liquid crystals in which the liquid crystallinity is enabled by halogen‐bonded supramolecular anions [C(n)F(2 n+1)‐I⋅⋅⋅I⋅⋅⋅I‐C(n)F(2 n+1)](−) are reported. The material system is unique in many ways, demonstrating for the first time 1) ionic, halogen‐bonded liquid crystals, and 2) imidazolium‐based ionic liquid crystals in which the occurrence of liquid crystallinity is not driven by the alkyl chains of the cation. |
format | Online Article Text |
id | pubmed-5021112 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-50211122016-09-23 Superfluorinated Ionic Liquid Crystals Based on Supramolecular, Halogen‐Bonded Anions Cavallo, Gabriella Terraneo, Giancarlo Monfredini, Alessandro Saccone, Marco Priimagi, Arri Pilati, Tullio Resnati, Giuseppe Metrangolo, Pierangelo Bruce, Duncan W. Angew Chem Int Ed Engl Communications Unconventional ionic liquid crystals in which the liquid crystallinity is enabled by halogen‐bonded supramolecular anions [C(n)F(2 n+1)‐I⋅⋅⋅I⋅⋅⋅I‐C(n)F(2 n+1)](−) are reported. The material system is unique in many ways, demonstrating for the first time 1) ionic, halogen‐bonded liquid crystals, and 2) imidazolium‐based ionic liquid crystals in which the occurrence of liquid crystallinity is not driven by the alkyl chains of the cation. John Wiley and Sons Inc. 2016-04-13 2016-05-17 /pmc/articles/PMC5021112/ /pubmed/27073033 http://dx.doi.org/10.1002/anie.201601278 Text en © 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial (http://creativecommons.org/licenses/by-nc/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes. |
spellingShingle | Communications Cavallo, Gabriella Terraneo, Giancarlo Monfredini, Alessandro Saccone, Marco Priimagi, Arri Pilati, Tullio Resnati, Giuseppe Metrangolo, Pierangelo Bruce, Duncan W. Superfluorinated Ionic Liquid Crystals Based on Supramolecular, Halogen‐Bonded Anions |
title | Superfluorinated Ionic Liquid Crystals Based on Supramolecular, Halogen‐Bonded Anions |
title_full | Superfluorinated Ionic Liquid Crystals Based on Supramolecular, Halogen‐Bonded Anions |
title_fullStr | Superfluorinated Ionic Liquid Crystals Based on Supramolecular, Halogen‐Bonded Anions |
title_full_unstemmed | Superfluorinated Ionic Liquid Crystals Based on Supramolecular, Halogen‐Bonded Anions |
title_short | Superfluorinated Ionic Liquid Crystals Based on Supramolecular, Halogen‐Bonded Anions |
title_sort | superfluorinated ionic liquid crystals based on supramolecular, halogen‐bonded anions |
topic | Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5021112/ https://www.ncbi.nlm.nih.gov/pubmed/27073033 http://dx.doi.org/10.1002/anie.201601278 |
work_keys_str_mv | AT cavallogabriella superfluorinatedionicliquidcrystalsbasedonsupramolecularhalogenbondedanions AT terraneogiancarlo superfluorinatedionicliquidcrystalsbasedonsupramolecularhalogenbondedanions AT monfredinialessandro superfluorinatedionicliquidcrystalsbasedonsupramolecularhalogenbondedanions AT sacconemarco superfluorinatedionicliquidcrystalsbasedonsupramolecularhalogenbondedanions AT priimagiarri superfluorinatedionicliquidcrystalsbasedonsupramolecularhalogenbondedanions AT pilatitullio superfluorinatedionicliquidcrystalsbasedonsupramolecularhalogenbondedanions AT resnatigiuseppe superfluorinatedionicliquidcrystalsbasedonsupramolecularhalogenbondedanions AT metrangolopierangelo superfluorinatedionicliquidcrystalsbasedonsupramolecularhalogenbondedanions AT bruceduncanw superfluorinatedionicliquidcrystalsbasedonsupramolecularhalogenbondedanions |