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Superfluorinated Ionic Liquid Crystals Based on Supramolecular, Halogen‐Bonded Anions

Unconventional ionic liquid crystals in which the liquid crystallinity is enabled by halogen‐bonded supramolecular anions [C(n)F(2 n+1)‐I⋅⋅⋅I⋅⋅⋅I‐C(n)F(2 n+1)](−) are reported. The material system is unique in many ways, demonstrating for the first time 1) ionic, halogen‐bonded liquid crystals, and...

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Autores principales: Cavallo, Gabriella, Terraneo, Giancarlo, Monfredini, Alessandro, Saccone, Marco, Priimagi, Arri, Pilati, Tullio, Resnati, Giuseppe, Metrangolo, Pierangelo, Bruce, Duncan W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5021112/
https://www.ncbi.nlm.nih.gov/pubmed/27073033
http://dx.doi.org/10.1002/anie.201601278
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author Cavallo, Gabriella
Terraneo, Giancarlo
Monfredini, Alessandro
Saccone, Marco
Priimagi, Arri
Pilati, Tullio
Resnati, Giuseppe
Metrangolo, Pierangelo
Bruce, Duncan W.
author_facet Cavallo, Gabriella
Terraneo, Giancarlo
Monfredini, Alessandro
Saccone, Marco
Priimagi, Arri
Pilati, Tullio
Resnati, Giuseppe
Metrangolo, Pierangelo
Bruce, Duncan W.
author_sort Cavallo, Gabriella
collection PubMed
description Unconventional ionic liquid crystals in which the liquid crystallinity is enabled by halogen‐bonded supramolecular anions [C(n)F(2 n+1)‐I⋅⋅⋅I⋅⋅⋅I‐C(n)F(2 n+1)](−) are reported. The material system is unique in many ways, demonstrating for the first time 1) ionic, halogen‐bonded liquid crystals, and 2) imidazolium‐based ionic liquid crystals in which the occurrence of liquid crystallinity is not driven by the alkyl chains of the cation.
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spelling pubmed-50211122016-09-23 Superfluorinated Ionic Liquid Crystals Based on Supramolecular, Halogen‐Bonded Anions Cavallo, Gabriella Terraneo, Giancarlo Monfredini, Alessandro Saccone, Marco Priimagi, Arri Pilati, Tullio Resnati, Giuseppe Metrangolo, Pierangelo Bruce, Duncan W. Angew Chem Int Ed Engl Communications Unconventional ionic liquid crystals in which the liquid crystallinity is enabled by halogen‐bonded supramolecular anions [C(n)F(2 n+1)‐I⋅⋅⋅I⋅⋅⋅I‐C(n)F(2 n+1)](−) are reported. The material system is unique in many ways, demonstrating for the first time 1) ionic, halogen‐bonded liquid crystals, and 2) imidazolium‐based ionic liquid crystals in which the occurrence of liquid crystallinity is not driven by the alkyl chains of the cation. John Wiley and Sons Inc. 2016-04-13 2016-05-17 /pmc/articles/PMC5021112/ /pubmed/27073033 http://dx.doi.org/10.1002/anie.201601278 Text en © 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial (http://creativecommons.org/licenses/by-nc/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Communications
Cavallo, Gabriella
Terraneo, Giancarlo
Monfredini, Alessandro
Saccone, Marco
Priimagi, Arri
Pilati, Tullio
Resnati, Giuseppe
Metrangolo, Pierangelo
Bruce, Duncan W.
Superfluorinated Ionic Liquid Crystals Based on Supramolecular, Halogen‐Bonded Anions
title Superfluorinated Ionic Liquid Crystals Based on Supramolecular, Halogen‐Bonded Anions
title_full Superfluorinated Ionic Liquid Crystals Based on Supramolecular, Halogen‐Bonded Anions
title_fullStr Superfluorinated Ionic Liquid Crystals Based on Supramolecular, Halogen‐Bonded Anions
title_full_unstemmed Superfluorinated Ionic Liquid Crystals Based on Supramolecular, Halogen‐Bonded Anions
title_short Superfluorinated Ionic Liquid Crystals Based on Supramolecular, Halogen‐Bonded Anions
title_sort superfluorinated ionic liquid crystals based on supramolecular, halogen‐bonded anions
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5021112/
https://www.ncbi.nlm.nih.gov/pubmed/27073033
http://dx.doi.org/10.1002/anie.201601278
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