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Synthesis and Isolation of the Titanium–Scandium Endohedral Fullerenes—Sc(2)TiC@I(h)‐C(80), Sc(2)TiC@D (5h)‐C(80) and Sc(2)TiC(2)@I(h)‐C(80): Metal Size Tuning of the Ti(IV)/Ti(III) Redox Potentials
The formation of endohedral metallofullerenes (EMFs) in an electric arc is reported for the mixed‐metal Sc–Ti system utilizing methane as a reactive gas. Comparison of these results with those from the Sc/CH(4) and Ti/CH(4) systems as well as syntheses without methane revealed a strong mutual influe...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5029561/ https://www.ncbi.nlm.nih.gov/pubmed/27459520 http://dx.doi.org/10.1002/chem.201601655 |