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Carbohydrates as enantioinduction components in stereoselective catalysis

Carbohydrate derivatives are readily available chiral molecules, yet they are infrequently employed as enantioinduction components in stereoselective catalysis. In this review, synthetic approaches to carbohydrate-based ligands and catalysts are outlined, along with example applications in enantiose...

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Detalles Bibliográficos
Autores principales: Henderson, Alexander S., Bower, John F., Galan, M. Carmen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5048738/
https://www.ncbi.nlm.nih.gov/pubmed/27064817
http://dx.doi.org/10.1039/c6ob00368k
Descripción
Sumario:Carbohydrate derivatives are readily available chiral molecules, yet they are infrequently employed as enantioinduction components in stereoselective catalysis. In this review, synthetic approaches to carbohydrate-based ligands and catalysts are outlined, along with example applications in enantioselective catalysis. A wide range of carbohydrate-based functionality is covered, and key trends and future opportunities are identified.