Selective Phosphonylation of 5′-Adenosine Monophosphate (5′-AMP) via Pyrophosphite [PPi(III)]

We describe here experiments which demonstrate the selective phospho-transfer from a plausibly prebiotic condensed phosphorus (P) salt, pyrophosphite [H(2)P(2)O(5) (2−); PPi(III)], to the phosphate group of 5′-adenosine mono phosphate (5′-AMP). We show further that this P-transfer process is acceler...

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Detalles Bibliográficos
Autores principales: Kaye, Karl, Bryant, David E., Marriott, Katie E. R., Ohara, Shohei, Fishwick, Colin W. G., Kee, Terence P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Netherlands 2016
Materias:
Astrobiology
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050244/
https://www.ncbi.nlm.nih.gov/pubmed/27220497
http://dx.doi.org/10.1007/s11084-016-9497-y

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050244/
https://www.ncbi.nlm.nih.gov/pubmed/27220497
http://dx.doi.org/10.1007/s11084-016-9497-y

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