Supra­molecular inter­actions in the 1:2 co-crystal of 4,4′-bipyridine and 3-chloro­thio­phene-2-carb­oxy­lic acid

The asymmetric unit of the title compound, 2C(5)H(3)ClO(2)S·C(10)H(8)N(2), is comprised of a mol­ecule of 3-chloro­thio­phene-2-carb­oxy­lic acid (3TPC) and half of a mol­ecule of 4,4′-bi­pyridine (BPY). A distinctive O—H⋯N-based synthon is present. Cl⋯Cl and π–π stacking inter­actions further stabi...

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Autores principales: Prajina, Olakkandiyil, Thomas Muthiah, Packianathan, Geiger, David K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050753/
https://www.ncbi.nlm.nih.gov/pubmed/27746918
http://dx.doi.org/10.1107/S2056989016013724
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author Prajina, Olakkandiyil
Thomas Muthiah, Packianathan
Geiger, David K.
author_facet Prajina, Olakkandiyil
Thomas Muthiah, Packianathan
Geiger, David K.
author_sort Prajina, Olakkandiyil
collection PubMed
description The asymmetric unit of the title compound, 2C(5)H(3)ClO(2)S·C(10)H(8)N(2), is comprised of a mol­ecule of 3-chloro­thio­phene-2-carb­oxy­lic acid (3TPC) and half of a mol­ecule of 4,4′-bi­pyridine (BPY). A distinctive O—H⋯N-based synthon is present. Cl⋯Cl and π–π stacking inter­actions further stabilize the crystal structure, forming a two-dimensional network parallel to the bc plane.
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spelling pubmed-50507532016-10-14 Supra­molecular inter­actions in the 1:2 co-crystal of 4,4′-bipyridine and 3-chloro­thio­phene-2-carb­oxy­lic acid Prajina, Olakkandiyil Thomas Muthiah, Packianathan Geiger, David K. Acta Crystallogr E Crystallogr Commun Research Communications The asymmetric unit of the title compound, 2C(5)H(3)ClO(2)S·C(10)H(8)N(2), is comprised of a mol­ecule of 3-chloro­thio­phene-2-carb­oxy­lic acid (3TPC) and half of a mol­ecule of 4,4′-bi­pyridine (BPY). A distinctive O—H⋯N-based synthon is present. Cl⋯Cl and π–π stacking inter­actions further stabilize the crystal structure, forming a two-dimensional network parallel to the bc plane. International Union of Crystallography 2016-09-05 /pmc/articles/PMC5050753/ /pubmed/27746918 http://dx.doi.org/10.1107/S2056989016013724 Text en © Prajina et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Prajina, Olakkandiyil
Thomas Muthiah, Packianathan
Geiger, David K.
Supra­molecular inter­actions in the 1:2 co-crystal of 4,4′-bipyridine and 3-chloro­thio­phene-2-carb­oxy­lic acid
title Supra­molecular inter­actions in the 1:2 co-crystal of 4,4′-bipyridine and 3-chloro­thio­phene-2-carb­oxy­lic acid
title_full Supra­molecular inter­actions in the 1:2 co-crystal of 4,4′-bipyridine and 3-chloro­thio­phene-2-carb­oxy­lic acid
title_fullStr Supra­molecular inter­actions in the 1:2 co-crystal of 4,4′-bipyridine and 3-chloro­thio­phene-2-carb­oxy­lic acid
title_full_unstemmed Supra­molecular inter­actions in the 1:2 co-crystal of 4,4′-bipyridine and 3-chloro­thio­phene-2-carb­oxy­lic acid
title_short Supra­molecular inter­actions in the 1:2 co-crystal of 4,4′-bipyridine and 3-chloro­thio­phene-2-carb­oxy­lic acid
title_sort supra­molecular inter­actions in the 1:2 co-crystal of 4,4′-bipyridine and 3-chloro­thio­phene-2-carb­oxy­lic acid
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050753/
https://www.ncbi.nlm.nih.gov/pubmed/27746918
http://dx.doi.org/10.1107/S2056989016013724
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AT geigerdavidk supramolecularinteractionsinthe12cocrystalof44bipyridineand3chlorothiophene2carboxylicacid

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