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Crystal structure of 9,9′-{(1E,1′E)-[1,4-phenyl­enebis(aza­nylyl­idene)]bis­(methanylyl­idene)}bis­(2,3,6,7-tetra­hydro-1H,5H-pyrido[3,2,1-ij]quinolin-8-ol)

The whole mol­ecule of the title compound, C(32)H(34)N(2)O(2), is generated by inversion symmetry; the central benzene ring being situated about the crystallographic inversion center. The aromatic ring of the julolidine moiety is inclined to the central benzene ring by 33.70 (12)°. There are two int...

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Detalles Bibliográficos
Autores principales: Faizi, Md. Serajul Haque, Ali, Akram, Potaskalov, Vadim A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050754/
https://www.ncbi.nlm.nih.gov/pubmed/27746919
http://dx.doi.org/10.1107/S205698901601344X
Descripción
Sumario:The whole mol­ecule of the title compound, C(32)H(34)N(2)O(2), is generated by inversion symmetry; the central benzene ring being situated about the crystallographic inversion center. The aromatic ring of the julolidine moiety is inclined to the central benzene ring by 33.70 (12)°. There are two intra­molecular O—H⋯N hydrogen bonds in the mol­ecule, generating S(6) ring motifs. The conformation about the C=N bonds is E. The fused non-aromatic rings of the julolidine moiety adopt half-chair conformations. In the crystal, adjacent mol­ecules are linked by pairs of C—H⋯π inter­actions, forming a ladder-like structure propagating along the a-axis direction.