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Crystal structure of 9,9′-{(1E,1′E)-[1,4-phenyl­enebis(aza­nylyl­idene)]bis­(methanylyl­idene)}bis­(2,3,6,7-tetra­hydro-1H,5H-pyrido[3,2,1-ij]quinolin-8-ol)

The whole mol­ecule of the title compound, C(32)H(34)N(2)O(2), is generated by inversion symmetry; the central benzene ring being situated about the crystallographic inversion center. The aromatic ring of the julolidine moiety is inclined to the central benzene ring by 33.70 (12)°. There are two int...

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Autores principales: Faizi, Md. Serajul Haque, Ali, Akram, Potaskalov, Vadim A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050754/
https://www.ncbi.nlm.nih.gov/pubmed/27746919
http://dx.doi.org/10.1107/S205698901601344X
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author Faizi, Md. Serajul Haque
Ali, Akram
Potaskalov, Vadim A.
author_facet Faizi, Md. Serajul Haque
Ali, Akram
Potaskalov, Vadim A.
author_sort Faizi, Md. Serajul Haque
collection PubMed
description The whole mol­ecule of the title compound, C(32)H(34)N(2)O(2), is generated by inversion symmetry; the central benzene ring being situated about the crystallographic inversion center. The aromatic ring of the julolidine moiety is inclined to the central benzene ring by 33.70 (12)°. There are two intra­molecular O—H⋯N hydrogen bonds in the mol­ecule, generating S(6) ring motifs. The conformation about the C=N bonds is E. The fused non-aromatic rings of the julolidine moiety adopt half-chair conformations. In the crystal, adjacent mol­ecules are linked by pairs of C—H⋯π inter­actions, forming a ladder-like structure propagating along the a-axis direction.
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spelling pubmed-50507542016-10-14 Crystal structure of 9,9′-{(1E,1′E)-[1,4-phenyl­enebis(aza­nylyl­idene)]bis­(methanylyl­idene)}bis­(2,3,6,7-tetra­hydro-1H,5H-pyrido[3,2,1-ij]quinolin-8-ol) Faizi, Md. Serajul Haque Ali, Akram Potaskalov, Vadim A. Acta Crystallogr E Crystallogr Commun Research Communications The whole mol­ecule of the title compound, C(32)H(34)N(2)O(2), is generated by inversion symmetry; the central benzene ring being situated about the crystallographic inversion center. The aromatic ring of the julolidine moiety is inclined to the central benzene ring by 33.70 (12)°. There are two intra­molecular O—H⋯N hydrogen bonds in the mol­ecule, generating S(6) ring motifs. The conformation about the C=N bonds is E. The fused non-aromatic rings of the julolidine moiety adopt half-chair conformations. In the crystal, adjacent mol­ecules are linked by pairs of C—H⋯π inter­actions, forming a ladder-like structure propagating along the a-axis direction. International Union of Crystallography 2016-09-05 /pmc/articles/PMC5050754/ /pubmed/27746919 http://dx.doi.org/10.1107/S205698901601344X Text en © Faizi et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Faizi, Md. Serajul Haque
Ali, Akram
Potaskalov, Vadim A.
Crystal structure of 9,9′-{(1E,1′E)-[1,4-phenyl­enebis(aza­nylyl­idene)]bis­(methanylyl­idene)}bis­(2,3,6,7-tetra­hydro-1H,5H-pyrido[3,2,1-ij]quinolin-8-ol)
title Crystal structure of 9,9′-{(1E,1′E)-[1,4-phenyl­enebis(aza­nylyl­idene)]bis­(methanylyl­idene)}bis­(2,3,6,7-tetra­hydro-1H,5H-pyrido[3,2,1-ij]quinolin-8-ol)
title_full Crystal structure of 9,9′-{(1E,1′E)-[1,4-phenyl­enebis(aza­nylyl­idene)]bis­(methanylyl­idene)}bis­(2,3,6,7-tetra­hydro-1H,5H-pyrido[3,2,1-ij]quinolin-8-ol)
title_fullStr Crystal structure of 9,9′-{(1E,1′E)-[1,4-phenyl­enebis(aza­nylyl­idene)]bis­(methanylyl­idene)}bis­(2,3,6,7-tetra­hydro-1H,5H-pyrido[3,2,1-ij]quinolin-8-ol)
title_full_unstemmed Crystal structure of 9,9′-{(1E,1′E)-[1,4-phenyl­enebis(aza­nylyl­idene)]bis­(methanylyl­idene)}bis­(2,3,6,7-tetra­hydro-1H,5H-pyrido[3,2,1-ij]quinolin-8-ol)
title_short Crystal structure of 9,9′-{(1E,1′E)-[1,4-phenyl­enebis(aza­nylyl­idene)]bis­(methanylyl­idene)}bis­(2,3,6,7-tetra­hydro-1H,5H-pyrido[3,2,1-ij]quinolin-8-ol)
title_sort crystal structure of 9,9′-{(1e,1′e)-[1,4-phenyl­enebis(aza­nylyl­idene)]bis­(methanylyl­idene)}bis­(2,3,6,7-tetra­hydro-1h,5h-pyrido[3,2,1-ij]quinolin-8-ol)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050754/
https://www.ncbi.nlm.nih.gov/pubmed/27746919
http://dx.doi.org/10.1107/S205698901601344X
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