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Crystal structure of trans-diaquabis(4-cyanobenzoato-κO)bis(N,N-diethylnicotinamide-κN)zinc(II)
In the title complex, [Zn(C(8)H(4)NO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Zn(II) cation, located on an inversion centre, is coordinated by two water molecules, two 4-cyanobenzoate (CB) anions and two diethylnicotinamide (DENA) ligands in a distorted N(2)O(4) octahedral geometry. In the mo...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050756/ https://www.ncbi.nlm.nih.gov/pubmed/27746921 http://dx.doi.org/10.1107/S2056989016013815 |
Sumario: | In the title complex, [Zn(C(8)H(4)NO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Zn(II) cation, located on an inversion centre, is coordinated by two water molecules, two 4-cyanobenzoate (CB) anions and two diethylnicotinamide (DENA) ligands in a distorted N(2)O(4) octahedral geometry. In the molecule, the dihedral angle between the planar carboxylate group and the adjacent benzene ring is 9.50 (14)°, while the benzene and pyridine rings are oriented at a dihedral angle of 56.99 (5)°. The water molecules exhibit both an intramolecular hydrogen bond [to the non-coordinating carboxylate O atom, enclosing an S(6) hydrogen-bonding motif, where O⋯O = 2.6419 (19) Å] and an intermolecular hydrogen bond [to the amide carbonyl O atom, enclosing an R (2) (2)(16) ring motif, where O⋯O = 2.827 (2) Å]; the latter lead to the formation of supramolecular chains propagating along the [110] direction. |
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