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Crystal structure of trans-di­aqua­bis­(4-cyano­benzoato-κO)bis­(N,N-di­ethyl­nicotinamide-κN)zinc(II)

In the title complex, [Zn(C(8)H(4)NO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Zn(II) cation, located on an inversion centre, is coordinated by two water mol­ecules, two 4-cyano­benzoate (CB) anions and two di­ethyl­nicotinamide (DENA) ligands in a distorted N(2)O(4) octa­hedral geometry. In the mo...

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Autores principales: Akduran, Nurcan, Necefoğlu, Hacali, Aydoğdu, Ömer, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050756/
https://www.ncbi.nlm.nih.gov/pubmed/27746921
http://dx.doi.org/10.1107/S2056989016013815
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author Akduran, Nurcan
Necefoğlu, Hacali
Aydoğdu, Ömer
Hökelek, Tuncer
author_facet Akduran, Nurcan
Necefoğlu, Hacali
Aydoğdu, Ömer
Hökelek, Tuncer
author_sort Akduran, Nurcan
collection PubMed
description In the title complex, [Zn(C(8)H(4)NO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Zn(II) cation, located on an inversion centre, is coordinated by two water mol­ecules, two 4-cyano­benzoate (CB) anions and two di­ethyl­nicotinamide (DENA) ligands in a distorted N(2)O(4) octa­hedral geometry. In the mol­ecule, the dihedral angle between the planar carboxyl­ate group and the adjacent benzene ring is 9.50 (14)°, while the benzene and pyridine rings are oriented at a dihedral angle of 56.99 (5)°. The water mol­ecules exhibit both an intra­molecular hydrogen bond [to the non-coordinating carboxyl­ate O atom, enclosing an S(6) hydrogen-bonding motif, where O⋯O = 2.6419 (19) Å] and an inter­molecular hydrogen bond [to the amide carbonyl O atom, enclosing an R (2) (2)(16) ring motif, where O⋯O = 2.827 (2) Å]; the latter lead to the formation of supra­molecular chains propagating along the [110] direction.
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spelling pubmed-50507562016-10-14 Crystal structure of trans-di­aqua­bis­(4-cyano­benzoato-κO)bis­(N,N-di­ethyl­nicotinamide-κN)zinc(II) Akduran, Nurcan Necefoğlu, Hacali Aydoğdu, Ömer Hökelek, Tuncer Acta Crystallogr E Crystallogr Commun Research Communications In the title complex, [Zn(C(8)H(4)NO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Zn(II) cation, located on an inversion centre, is coordinated by two water mol­ecules, two 4-cyano­benzoate (CB) anions and two di­ethyl­nicotinamide (DENA) ligands in a distorted N(2)O(4) octa­hedral geometry. In the mol­ecule, the dihedral angle between the planar carboxyl­ate group and the adjacent benzene ring is 9.50 (14)°, while the benzene and pyridine rings are oriented at a dihedral angle of 56.99 (5)°. The water mol­ecules exhibit both an intra­molecular hydrogen bond [to the non-coordinating carboxyl­ate O atom, enclosing an S(6) hydrogen-bonding motif, where O⋯O = 2.6419 (19) Å] and an inter­molecular hydrogen bond [to the amide carbonyl O atom, enclosing an R (2) (2)(16) ring motif, where O⋯O = 2.827 (2) Å]; the latter lead to the formation of supra­molecular chains propagating along the [110] direction. International Union of Crystallography 2016-09-05 /pmc/articles/PMC5050756/ /pubmed/27746921 http://dx.doi.org/10.1107/S2056989016013815 Text en © Akduran et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Akduran, Nurcan
Necefoğlu, Hacali
Aydoğdu, Ömer
Hökelek, Tuncer
Crystal structure of trans-di­aqua­bis­(4-cyano­benzoato-κO)bis­(N,N-di­ethyl­nicotinamide-κN)zinc(II)
title Crystal structure of trans-di­aqua­bis­(4-cyano­benzoato-κO)bis­(N,N-di­ethyl­nicotinamide-κN)zinc(II)
title_full Crystal structure of trans-di­aqua­bis­(4-cyano­benzoato-κO)bis­(N,N-di­ethyl­nicotinamide-κN)zinc(II)
title_fullStr Crystal structure of trans-di­aqua­bis­(4-cyano­benzoato-κO)bis­(N,N-di­ethyl­nicotinamide-κN)zinc(II)
title_full_unstemmed Crystal structure of trans-di­aqua­bis­(4-cyano­benzoato-κO)bis­(N,N-di­ethyl­nicotinamide-κN)zinc(II)
title_short Crystal structure of trans-di­aqua­bis­(4-cyano­benzoato-κO)bis­(N,N-di­ethyl­nicotinamide-κN)zinc(II)
title_sort crystal structure of trans-di­aqua­bis­(4-cyano­benzoato-κo)bis­(n,n-di­ethyl­nicotinamide-κn)zinc(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050756/
https://www.ncbi.nlm.nih.gov/pubmed/27746921
http://dx.doi.org/10.1107/S2056989016013815
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