Crystal structure of 2-[2-(2,5-di­chloro­benz­yloxy)-2-(furan-2-yl)eth­yl]-2H-indazole

In the title compound, C(20)H(16)Cl(2)N(2)O(2), the indazole ring system is approximately planar [maximum deviation = 0.033 (1) Å], its mean plane is oriented at dihedral angles of 25.04 (4) and 5.10 (4)° to the furan and benzene rings, respectively. In the crystal, pairs of C—H(ind)⋯O(bo) (ind = in...

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Autores principales: Özel Güven, Özden, Türk, Gökhan, Adler, Philip D. F., Coles, Simon J., Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050757/
https://www.ncbi.nlm.nih.gov/pubmed/27746922
http://dx.doi.org/10.1107/S2056989016013827
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author Özel Güven, Özden
Türk, Gökhan
Adler, Philip D. F.
Coles, Simon J.
Hökelek, Tuncer
author_facet Özel Güven, Özden
Türk, Gökhan
Adler, Philip D. F.
Coles, Simon J.
Hökelek, Tuncer
author_sort Özel Güven, Özden
collection PubMed
description In the title compound, C(20)H(16)Cl(2)N(2)O(2), the indazole ring system is approximately planar [maximum deviation = 0.033 (1) Å], its mean plane is oriented at dihedral angles of 25.04 (4) and 5.10 (4)° to the furan and benzene rings, respectively. In the crystal, pairs of C—H(ind)⋯O(bo) (ind = indazole and bo = benz­yloxy) hydrogen bonds link the mol­ecules into centrosymmetric dimers with graph-set motif R (2) (2)(12). Weak C—H⋯π inter­actions is also observed. Aromatic π–π stacking between the benzene and the pyrazole rings from neighbouring mol­ecules [centroid–centroid distance = 3.8894 (7) Å] further consolidates the crystal packing.
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spelling pubmed-50507572016-10-14 Crystal structure of 2-[2-(2,5-di­chloro­benz­yloxy)-2-(furan-2-yl)eth­yl]-2H-indazole Özel Güven, Özden Türk, Gökhan Adler, Philip D. F. Coles, Simon J. Hökelek, Tuncer Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(20)H(16)Cl(2)N(2)O(2), the indazole ring system is approximately planar [maximum deviation = 0.033 (1) Å], its mean plane is oriented at dihedral angles of 25.04 (4) and 5.10 (4)° to the furan and benzene rings, respectively. In the crystal, pairs of C—H(ind)⋯O(bo) (ind = indazole and bo = benz­yloxy) hydrogen bonds link the mol­ecules into centrosymmetric dimers with graph-set motif R (2) (2)(12). Weak C—H⋯π inter­actions is also observed. Aromatic π–π stacking between the benzene and the pyrazole rings from neighbouring mol­ecules [centroid–centroid distance = 3.8894 (7) Å] further consolidates the crystal packing. International Union of Crystallography 2016-09-05 /pmc/articles/PMC5050757/ /pubmed/27746922 http://dx.doi.org/10.1107/S2056989016013827 Text en © Özel Güven et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Özel Güven, Özden
Türk, Gökhan
Adler, Philip D. F.
Coles, Simon J.
Hökelek, Tuncer
Crystal structure of 2-[2-(2,5-di­chloro­benz­yloxy)-2-(furan-2-yl)eth­yl]-2H-indazole
title Crystal structure of 2-[2-(2,5-di­chloro­benz­yloxy)-2-(furan-2-yl)eth­yl]-2H-indazole
title_full Crystal structure of 2-[2-(2,5-di­chloro­benz­yloxy)-2-(furan-2-yl)eth­yl]-2H-indazole
title_fullStr Crystal structure of 2-[2-(2,5-di­chloro­benz­yloxy)-2-(furan-2-yl)eth­yl]-2H-indazole
title_full_unstemmed Crystal structure of 2-[2-(2,5-di­chloro­benz­yloxy)-2-(furan-2-yl)eth­yl]-2H-indazole
title_short Crystal structure of 2-[2-(2,5-di­chloro­benz­yloxy)-2-(furan-2-yl)eth­yl]-2H-indazole
title_sort crystal structure of 2-[2-(2,5-di­chloro­benz­yloxy)-2-(furan-2-yl)eth­yl]-2h-indazole
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050757/
https://www.ncbi.nlm.nih.gov/pubmed/27746922
http://dx.doi.org/10.1107/S2056989016013827
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