Crystal structure of (OC)(5)W(μ-dppe)W(CO)(5)

The centrosymmetric title complex, [μ-ethane-1,2-diylbis(di­phenyl­phosphane)-κ(2) P:P′]bis­[penta­carbonyl­tungsten(0)], [W(2)(C(26)H(24)P(2))(CO)(10)], consists of two W(CO)(5) moieties bridged by a bis­(di­phenyl­phosphan­yl)ethane (dppe) ligand. The W(0) atom has a slightly distorted octa­hedral...

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Detalles Bibliográficos
Autores principales: Drake, Hannah F., Wheeler, Kraig A., Bellott, Brian J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050759/
https://www.ncbi.nlm.nih.gov/pubmed/27746924
http://dx.doi.org/10.1107/S2056989016013670
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author Drake, Hannah F.
Wheeler, Kraig A.
Bellott, Brian J.
author_facet Drake, Hannah F.
Wheeler, Kraig A.
Bellott, Brian J.
author_sort Drake, Hannah F.
collection PubMed
description The centrosymmetric title complex, [μ-ethane-1,2-diylbis(di­phenyl­phosphane)-κ(2) P:P′]bis­[penta­carbonyl­tungsten(0)], [W(2)(C(26)H(24)P(2))(CO)(10)], consists of two W(CO)(5) moieties bridged by a bis­(di­phenyl­phosphan­yl)ethane (dppe) ligand. The W(0) atom has a slightly distorted octa­hedral coordination environment consisting of 5 carbonyl ligands and one P atom from the bridging dppe ligand with the nearest W(0) atom 5.625 (5) Å away. The complex resides on a center of symmetry.
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spelling pubmed-50507592016-10-14 Crystal structure of (OC)(5)W(μ-dppe)W(CO)(5) Drake, Hannah F. Wheeler, Kraig A. Bellott, Brian J. Acta Crystallogr E Crystallogr Commun Research Communications The centrosymmetric title complex, [μ-ethane-1,2-diylbis(di­phenyl­phosphane)-κ(2) P:P′]bis­[penta­carbonyl­tungsten(0)], [W(2)(C(26)H(24)P(2))(CO)(10)], consists of two W(CO)(5) moieties bridged by a bis­(di­phenyl­phosphan­yl)ethane (dppe) ligand. The W(0) atom has a slightly distorted octa­hedral coordination environment consisting of 5 carbonyl ligands and one P atom from the bridging dppe ligand with the nearest W(0) atom 5.625 (5) Å away. The complex resides on a center of symmetry. International Union of Crystallography 2016-09-05 /pmc/articles/PMC5050759/ /pubmed/27746924 http://dx.doi.org/10.1107/S2056989016013670 Text en © Drake et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Drake, Hannah F.
Wheeler, Kraig A.
Bellott, Brian J.
Crystal structure of (OC)(5)W(μ-dppe)W(CO)(5)
title Crystal structure of (OC)(5)W(μ-dppe)W(CO)(5)
title_full Crystal structure of (OC)(5)W(μ-dppe)W(CO)(5)
title_fullStr Crystal structure of (OC)(5)W(μ-dppe)W(CO)(5)
title_full_unstemmed Crystal structure of (OC)(5)W(μ-dppe)W(CO)(5)
title_short Crystal structure of (OC)(5)W(μ-dppe)W(CO)(5)
title_sort crystal structure of (oc)(5)w(μ-dppe)w(co)(5)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050759/
https://www.ncbi.nlm.nih.gov/pubmed/27746924
http://dx.doi.org/10.1107/S2056989016013670
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