Crystal structure of μ-4-oxidobenzoato-κ(2) O (1):O (4)-bis­[bis­(1,10-phenanthroline-κ(2) N,N′)copper(II)] bis­(4-hy­droxy­benzoate) 7.5-hydrate

The title hydrated complex, [Cu(2)(C(7)H(4)O(3))(C(12)H(8)N(2))(4)](C(7)H(5)O(3))(2)·7.5H(2)O, is composed of dinuclear Cu(II) complex cations, noncoordinating 4-hy­droxy­benzoate anions and water mol­ecules of crystallization. In the dinuclear complex cation, the Cu(II) ions are bridged by a 4-oxid...

Descripción completa

Detalles Bibliográficos
Autores principales: Su, Jian-Rong, Li, Yu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050762/
https://www.ncbi.nlm.nih.gov/pubmed/27746927
http://dx.doi.org/10.1107/S2056989016013943
_version_ 1782457946116980736
author Su, Jian-Rong
Li, Yu
author_facet Su, Jian-Rong
Li, Yu
author_sort Su, Jian-Rong
collection PubMed
description The title hydrated complex, [Cu(2)(C(7)H(4)O(3))(C(12)H(8)N(2))(4)](C(7)H(5)O(3))(2)·7.5H(2)O, is composed of dinuclear Cu(II) complex cations, noncoordinating 4-hy­droxy­benzoate anions and water mol­ecules of crystallization. In the dinuclear complex cation, the Cu(II) ions are bridged by a 4-oxidobenzoate ligand and thus each metal ion is five-coordinated by two chelating 1,10-phenanthroline (phen) mol­ecules and one anionic O atom in a distorted trigonal-bipyramid geometry. In the crystal, aromatic π–π stacking occurs between phen rings of neighbouring dinuclear Cu(II) complex cations, forming two-dimensional supra­molecular systems parallel to (100).
format Online
Article
Text
id pubmed-5050762
institution National Center for Biotechnology Information
language English
publishDate 2016
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-50507622016-10-14 Crystal structure of μ-4-oxidobenzoato-κ(2) O (1):O (4)-bis­[bis­(1,10-phenanthroline-κ(2) N,N′)copper(II)] bis­(4-hy­droxy­benzoate) 7.5-hydrate Su, Jian-Rong Li, Yu Acta Crystallogr E Crystallogr Commun Research Communications The title hydrated complex, [Cu(2)(C(7)H(4)O(3))(C(12)H(8)N(2))(4)](C(7)H(5)O(3))(2)·7.5H(2)O, is composed of dinuclear Cu(II) complex cations, noncoordinating 4-hy­droxy­benzoate anions and water mol­ecules of crystallization. In the dinuclear complex cation, the Cu(II) ions are bridged by a 4-oxidobenzoate ligand and thus each metal ion is five-coordinated by two chelating 1,10-phenanthroline (phen) mol­ecules and one anionic O atom in a distorted trigonal-bipyramid geometry. In the crystal, aromatic π–π stacking occurs between phen rings of neighbouring dinuclear Cu(II) complex cations, forming two-dimensional supra­molecular systems parallel to (100). International Union of Crystallography 2016-09-05 /pmc/articles/PMC5050762/ /pubmed/27746927 http://dx.doi.org/10.1107/S2056989016013943 Text en © Su and Li 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Su, Jian-Rong
Li, Yu
Crystal structure of μ-4-oxidobenzoato-κ(2) O (1):O (4)-bis­[bis­(1,10-phenanthroline-κ(2) N,N′)copper(II)] bis­(4-hy­droxy­benzoate) 7.5-hydrate
title Crystal structure of μ-4-oxidobenzoato-κ(2) O (1):O (4)-bis­[bis­(1,10-phenanthroline-κ(2) N,N′)copper(II)] bis­(4-hy­droxy­benzoate) 7.5-hydrate
title_full Crystal structure of μ-4-oxidobenzoato-κ(2) O (1):O (4)-bis­[bis­(1,10-phenanthroline-κ(2) N,N′)copper(II)] bis­(4-hy­droxy­benzoate) 7.5-hydrate
title_fullStr Crystal structure of μ-4-oxidobenzoato-κ(2) O (1):O (4)-bis­[bis­(1,10-phenanthroline-κ(2) N,N′)copper(II)] bis­(4-hy­droxy­benzoate) 7.5-hydrate
title_full_unstemmed Crystal structure of μ-4-oxidobenzoato-κ(2) O (1):O (4)-bis­[bis­(1,10-phenanthroline-κ(2) N,N′)copper(II)] bis­(4-hy­droxy­benzoate) 7.5-hydrate
title_short Crystal structure of μ-4-oxidobenzoato-κ(2) O (1):O (4)-bis­[bis­(1,10-phenanthroline-κ(2) N,N′)copper(II)] bis­(4-hy­droxy­benzoate) 7.5-hydrate
title_sort crystal structure of μ-4-oxidobenzoato-κ(2) o (1):o (4)-bis­[bis­(1,10-phenanthroline-κ(2) n,n′)copper(ii)] bis­(4-hy­droxy­benzoate) 7.5-hydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050762/
https://www.ncbi.nlm.nih.gov/pubmed/27746927
http://dx.doi.org/10.1107/S2056989016013943
work_keys_str_mv AT sujianrong crystalstructureofm4oxidobenzoatok2o1o4bisbis110phenanthrolinek2nncopperiibis4hydroxybenzoate75hydrate
AT liyu crystalstructureofm4oxidobenzoatok2o1o4bisbis110phenanthrolinek2nncopperiibis4hydroxybenzoate75hydrate

Ejemplares similares