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Crystal structure of poly[{μ(3)-(E)-3-[3-(carboxylatomethoxy)phenyl]acrylato-κ(3) O,O′:O′′:O′′′}[μ(2)-3-(pyridin-4-yl)-1H-pyrazole-κ(2) N:N′]cobalt(II)]
The title compound, [Co(C(11)H(8)O(5))(C(8)H(7)N(3))](n), which is based on (E)-3-[3-(carboxymethoxy)phenyl]acrylic acid (H(2) L) and 3-(pyridin-4-yl)pyrazole (pp) ligands, has been synthesized under solvothermal conditions. The dihedral angle between pyrazole and pyridine rings in the pp ligand...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050769/ https://www.ncbi.nlm.nih.gov/pubmed/27746934 http://dx.doi.org/10.1107/S205698901601402X |
| _version_ | 1782457947754856448 |
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| author | Zhao, Can Li, Xiao-Zong Kang, Hong-Lan Wen, Yi-Hang |
| author_facet | Zhao, Can Li, Xiao-Zong Kang, Hong-Lan Wen, Yi-Hang |
| author_sort | Zhao, Can |
| collection | PubMed |
| description | The title compound, [Co(C(11)H(8)O(5))(C(8)H(7)N(3))](n), which is based on (E)-3-[3-(carboxymethoxy)phenyl]acrylic acid (H(2) L) and 3-(pyridin-4-yl)pyrazole (pp) ligands, has been synthesized under solvothermal conditions. The dihedral angle between pyrazole and pyridine rings in the pp ligands is 23.1 (2)°. In the crystal, helical chains formed by pp and L ligands connected to the Co(II) atom propagate parallel to the c axis. Co(II) atoms of adjacent chains are bridged by the acrylic acid groups of L ligands into corrugated polymeric sheets in the ac plane. |
| format | Online Article Text |
| id | pubmed-5050769 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2016 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-50507692016-10-14 Crystal structure of poly[{μ(3)-(E)-3-[3-(carboxylatomethoxy)phenyl]acrylato-κ(3) O,O′:O′′:O′′′}[μ(2)-3-(pyridin-4-yl)-1H-pyrazole-κ(2) N:N′]cobalt(II)] Zhao, Can Li, Xiao-Zong Kang, Hong-Lan Wen, Yi-Hang Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [Co(C(11)H(8)O(5))(C(8)H(7)N(3))](n), which is based on (E)-3-[3-(carboxymethoxy)phenyl]acrylic acid (H(2) L) and 3-(pyridin-4-yl)pyrazole (pp) ligands, has been synthesized under solvothermal conditions. The dihedral angle between pyrazole and pyridine rings in the pp ligands is 23.1 (2)°. In the crystal, helical chains formed by pp and L ligands connected to the Co(II) atom propagate parallel to the c axis. Co(II) atoms of adjacent chains are bridged by the acrylic acid groups of L ligands into corrugated polymeric sheets in the ac plane. International Union of Crystallography 2016-09-09 /pmc/articles/PMC5050769/ /pubmed/27746934 http://dx.doi.org/10.1107/S205698901601402X Text en © Zhao et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Zhao, Can Li, Xiao-Zong Kang, Hong-Lan Wen, Yi-Hang Crystal structure of poly[{μ(3)-(E)-3-[3-(carboxylatomethoxy)phenyl]acrylato-κ(3) O,O′:O′′:O′′′}[μ(2)-3-(pyridin-4-yl)-1H-pyrazole-κ(2) N:N′]cobalt(II)] |
| title | Crystal structure of poly[{μ(3)-(E)-3-[3-(carboxylatomethoxy)phenyl]acrylato-κ(3)
O,O′:O′′:O′′′}[μ(2)-3-(pyridin-4-yl)-1H-pyrazole-κ(2)
N:N′]cobalt(II)] |
| title_full | Crystal structure of poly[{μ(3)-(E)-3-[3-(carboxylatomethoxy)phenyl]acrylato-κ(3)
O,O′:O′′:O′′′}[μ(2)-3-(pyridin-4-yl)-1H-pyrazole-κ(2)
N:N′]cobalt(II)] |
| title_fullStr | Crystal structure of poly[{μ(3)-(E)-3-[3-(carboxylatomethoxy)phenyl]acrylato-κ(3)
O,O′:O′′:O′′′}[μ(2)-3-(pyridin-4-yl)-1H-pyrazole-κ(2)
N:N′]cobalt(II)] |
| title_full_unstemmed | Crystal structure of poly[{μ(3)-(E)-3-[3-(carboxylatomethoxy)phenyl]acrylato-κ(3)
O,O′:O′′:O′′′}[μ(2)-3-(pyridin-4-yl)-1H-pyrazole-κ(2)
N:N′]cobalt(II)] |
| title_short | Crystal structure of poly[{μ(3)-(E)-3-[3-(carboxylatomethoxy)phenyl]acrylato-κ(3)
O,O′:O′′:O′′′}[μ(2)-3-(pyridin-4-yl)-1H-pyrazole-κ(2)
N:N′]cobalt(II)] |
| title_sort | crystal structure of poly[{μ(3)-(e)-3-[3-(carboxylatomethoxy)phenyl]acrylato-κ(3)
o,o′:o′′:o′′′}[μ(2)-3-(pyridin-4-yl)-1h-pyrazole-κ(2)
n:n′]cobalt(ii)] |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050769/ https://www.ncbi.nlm.nih.gov/pubmed/27746934 http://dx.doi.org/10.1107/S205698901601402X |
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