Crystal structure of di­aqua­bis­(2-chloro­pyridine-κN)bis­(thio­cyanato-κN)nickel(II)

The asymmetric unit of the title compound, [Ni(NCS)(2)(C(5)H(4)ClN)(2)(H(2)O)(2)], consists of one nickel(II) cation that is located on a center of inversion and one thio­cyanate anion, one water mol­ecule and one 2-chloro­pyridine ligand all occupying general positions. The Ni(II) cation is octa­he...

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Detalles Bibliográficos
Autores principales: Suckert, Stefan, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050783/
https://www.ncbi.nlm.nih.gov/pubmed/27746948
http://dx.doi.org/10.1107/S2056989016015218
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author Suckert, Stefan
Jess, Inke
Näther, Christian
author_facet Suckert, Stefan
Jess, Inke
Näther, Christian
author_sort Suckert, Stefan
collection PubMed
description The asymmetric unit of the title compound, [Ni(NCS)(2)(C(5)H(4)ClN)(2)(H(2)O)(2)], consists of one nickel(II) cation that is located on a center of inversion and one thio­cyanate anion, one water mol­ecule and one 2-chloro­pyridine ligand all occupying general positions. The Ni(II) cation is octa­hedrally coordinated by two terminal N-bound thio­cyanato ligands, two aqua ligands and two N-bound 2-chloro­pyridine ligands into discrete complexes. Individual complexes are linked by inter­molecular O—H⋯S and O—H⋯Cl hydrogen-bonding inter­actions into a layered network extending parallel to the bc plane. Weak inter­actions of types C—H⋯S and C—H⋯Cl consolidate the crystal packing.
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spelling pubmed-50507832016-10-14 Crystal structure of di­aqua­bis­(2-chloro­pyridine-κN)bis­(thio­cyanato-κN)nickel(II) Suckert, Stefan Jess, Inke Näther, Christian Acta Crystallogr E Crystallogr Commun Research Communications The asymmetric unit of the title compound, [Ni(NCS)(2)(C(5)H(4)ClN)(2)(H(2)O)(2)], consists of one nickel(II) cation that is located on a center of inversion and one thio­cyanate anion, one water mol­ecule and one 2-chloro­pyridine ligand all occupying general positions. The Ni(II) cation is octa­hedrally coordinated by two terminal N-bound thio­cyanato ligands, two aqua ligands and two N-bound 2-chloro­pyridine ligands into discrete complexes. Individual complexes are linked by inter­molecular O—H⋯S and O—H⋯Cl hydrogen-bonding inter­actions into a layered network extending parallel to the bc plane. Weak inter­actions of types C—H⋯S and C—H⋯Cl consolidate the crystal packing. International Union of Crystallography 2016-09-30 /pmc/articles/PMC5050783/ /pubmed/27746948 http://dx.doi.org/10.1107/S2056989016015218 Text en © Suckert et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Suckert, Stefan
Jess, Inke
Näther, Christian
Crystal structure of di­aqua­bis­(2-chloro­pyridine-κN)bis­(thio­cyanato-κN)nickel(II)
title Crystal structure of di­aqua­bis­(2-chloro­pyridine-κN)bis­(thio­cyanato-κN)nickel(II)
title_full Crystal structure of di­aqua­bis­(2-chloro­pyridine-κN)bis­(thio­cyanato-κN)nickel(II)
title_fullStr Crystal structure of di­aqua­bis­(2-chloro­pyridine-κN)bis­(thio­cyanato-κN)nickel(II)
title_full_unstemmed Crystal structure of di­aqua­bis­(2-chloro­pyridine-κN)bis­(thio­cyanato-κN)nickel(II)
title_short Crystal structure of di­aqua­bis­(2-chloro­pyridine-κN)bis­(thio­cyanato-κN)nickel(II)
title_sort crystal structure of di­aqua­bis­(2-chloro­pyridine-κn)bis­(thio­cyanato-κn)nickel(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050783/
https://www.ncbi.nlm.nih.gov/pubmed/27746948
http://dx.doi.org/10.1107/S2056989016015218
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