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Synthesis and crystal structure of bis(1-{[(quinolin-8-yl)imino]methyl}pyrene-κ(2) N,N′)silver(I) trifluoromethanesulfonate
The title compound, [Ag(qPyr)(2)]CF(3)SO(3) where qPyr = 1-(quinoline-2-ylmethylene)aminopyrene, C(26)H(16)N(2), was synthesized from a reaction of silver trifluoromethanesulfonate and qPyr in dichloromethane–methanol mixed media. In this design, the qPyr ligand was chosen for its characteri...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050784/ https://www.ncbi.nlm.nih.gov/pubmed/27746949 http://dx.doi.org/10.1107/S205698901601519X |
Sumario: | The title compound, [Ag(qPyr)(2)]CF(3)SO(3) where qPyr = 1-(quinoline-2-ylmethylene)aminopyrene, C(26)H(16)N(2), was synthesized from a reaction of silver trifluoromethanesulfonate and qPyr in dichloromethane–methanol mixed media. In this design, the qPyr ligand was chosen for its characteristic excitation and emission profiles, which could enable the tracking of the silver complex within biological targets. The Ag(I) atom resides in a distorted tetrahedral N(4) coordination sphere. Analysis of the packing pattern revealed significant intra- and intermolecular π–π stacking interactions between the [Ag(qPyr)(2)](+) cations. In addition, a weak C—H⋯O hydrogen bond consolidates the packing between cations and anions. |
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