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Synthesis and crystal structure of bis(1-{[(quinolin-8-yl)imino]methyl}pyrene-κ(2) N,N′)silver(I) tri­fluoro­methane­sulfonate

The title compound, [Ag(qPyr)(2)]CF(3)SO(3) where qPyr = 1-(quinoline-2-yl­methyl­ene)amino­pyrene, C(26)H(16)N(2), was synthesized from a reaction of silver tri­fluoro­methane­sulfonate and qPyr in di­chloro­methane–methanol mixed media. In this design, the qPyr ligand was chosen for its characteri...

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Detalles Bibliográficos
Autores principales: Pinto, Miguel, Chakraborty, Indranil, Mascharak, Pradip
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050784/
https://www.ncbi.nlm.nih.gov/pubmed/27746949
http://dx.doi.org/10.1107/S205698901601519X
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author Pinto, Miguel
Chakraborty, Indranil
Mascharak, Pradip
author_facet Pinto, Miguel
Chakraborty, Indranil
Mascharak, Pradip
author_sort Pinto, Miguel
collection PubMed
description The title compound, [Ag(qPyr)(2)]CF(3)SO(3) where qPyr = 1-(quinoline-2-yl­methyl­ene)amino­pyrene, C(26)H(16)N(2), was synthesized from a reaction of silver tri­fluoro­methane­sulfonate and qPyr in di­chloro­methane–methanol mixed media. In this design, the qPyr ligand was chosen for its characteristic excitation and emission profiles, which could enable the tracking of the silver complex within biological targets. The Ag(I) atom resides in a distorted tetra­hedral N(4) coordination sphere. Analysis of the packing pattern revealed significant intra- and inter­molecular π–π stacking inter­actions between the [Ag(qPyr)(2)](+) cations. In addition, a weak C—H⋯O hydrogen bond consolidates the packing between cations and anions.
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spelling pubmed-50507842016-10-14 Synthesis and crystal structure of bis(1-{[(quinolin-8-yl)imino]methyl}pyrene-κ(2) N,N′)silver(I) tri­fluoro­methane­sulfonate Pinto, Miguel Chakraborty, Indranil Mascharak, Pradip Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [Ag(qPyr)(2)]CF(3)SO(3) where qPyr = 1-(quinoline-2-yl­methyl­ene)amino­pyrene, C(26)H(16)N(2), was synthesized from a reaction of silver tri­fluoro­methane­sulfonate and qPyr in di­chloro­methane–methanol mixed media. In this design, the qPyr ligand was chosen for its characteristic excitation and emission profiles, which could enable the tracking of the silver complex within biological targets. The Ag(I) atom resides in a distorted tetra­hedral N(4) coordination sphere. Analysis of the packing pattern revealed significant intra- and inter­molecular π–π stacking inter­actions between the [Ag(qPyr)(2)](+) cations. In addition, a weak C—H⋯O hydrogen bond consolidates the packing between cations and anions. International Union of Crystallography 2016-09-30 /pmc/articles/PMC5050784/ /pubmed/27746949 http://dx.doi.org/10.1107/S205698901601519X Text en © Pinto et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Pinto, Miguel
Chakraborty, Indranil
Mascharak, Pradip
Synthesis and crystal structure of bis(1-{[(quinolin-8-yl)imino]methyl}pyrene-κ(2) N,N′)silver(I) tri­fluoro­methane­sulfonate
title Synthesis and crystal structure of bis(1-{[(quinolin-8-yl)imino]methyl}pyrene-κ(2) N,N′)silver(I) tri­fluoro­methane­sulfonate
title_full Synthesis and crystal structure of bis(1-{[(quinolin-8-yl)imino]methyl}pyrene-κ(2) N,N′)silver(I) tri­fluoro­methane­sulfonate
title_fullStr Synthesis and crystal structure of bis(1-{[(quinolin-8-yl)imino]methyl}pyrene-κ(2) N,N′)silver(I) tri­fluoro­methane­sulfonate
title_full_unstemmed Synthesis and crystal structure of bis(1-{[(quinolin-8-yl)imino]methyl}pyrene-κ(2) N,N′)silver(I) tri­fluoro­methane­sulfonate
title_short Synthesis and crystal structure of bis(1-{[(quinolin-8-yl)imino]methyl}pyrene-κ(2) N,N′)silver(I) tri­fluoro­methane­sulfonate
title_sort synthesis and crystal structure of bis(1-{[(quinolin-8-yl)imino]methyl}pyrene-κ(2) n,n′)silver(i) tri­fluoro­methane­sulfonate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050784/
https://www.ncbi.nlm.nih.gov/pubmed/27746949
http://dx.doi.org/10.1107/S205698901601519X
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