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Synthesis and crystal structure of bis(1-{[(quinolin-8-yl)imino]methyl}pyrene-κ(2) N,N′)silver(I) trifluoromethanesulfonate
The title compound, [Ag(qPyr)(2)]CF(3)SO(3) where qPyr = 1-(quinoline-2-ylmethylene)aminopyrene, C(26)H(16)N(2), was synthesized from a reaction of silver trifluoromethanesulfonate and qPyr in dichloromethane–methanol mixed media. In this design, the qPyr ligand was chosen for its characteri...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050784/ https://www.ncbi.nlm.nih.gov/pubmed/27746949 http://dx.doi.org/10.1107/S205698901601519X |
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author | Pinto, Miguel Chakraborty, Indranil Mascharak, Pradip |
author_facet | Pinto, Miguel Chakraborty, Indranil Mascharak, Pradip |
author_sort | Pinto, Miguel |
collection | PubMed |
description | The title compound, [Ag(qPyr)(2)]CF(3)SO(3) where qPyr = 1-(quinoline-2-ylmethylene)aminopyrene, C(26)H(16)N(2), was synthesized from a reaction of silver trifluoromethanesulfonate and qPyr in dichloromethane–methanol mixed media. In this design, the qPyr ligand was chosen for its characteristic excitation and emission profiles, which could enable the tracking of the silver complex within biological targets. The Ag(I) atom resides in a distorted tetrahedral N(4) coordination sphere. Analysis of the packing pattern revealed significant intra- and intermolecular π–π stacking interactions between the [Ag(qPyr)(2)](+) cations. In addition, a weak C—H⋯O hydrogen bond consolidates the packing between cations and anions. |
format | Online Article Text |
id | pubmed-5050784 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-50507842016-10-14 Synthesis and crystal structure of bis(1-{[(quinolin-8-yl)imino]methyl}pyrene-κ(2) N,N′)silver(I) trifluoromethanesulfonate Pinto, Miguel Chakraborty, Indranil Mascharak, Pradip Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [Ag(qPyr)(2)]CF(3)SO(3) where qPyr = 1-(quinoline-2-ylmethylene)aminopyrene, C(26)H(16)N(2), was synthesized from a reaction of silver trifluoromethanesulfonate and qPyr in dichloromethane–methanol mixed media. In this design, the qPyr ligand was chosen for its characteristic excitation and emission profiles, which could enable the tracking of the silver complex within biological targets. The Ag(I) atom resides in a distorted tetrahedral N(4) coordination sphere. Analysis of the packing pattern revealed significant intra- and intermolecular π–π stacking interactions between the [Ag(qPyr)(2)](+) cations. In addition, a weak C—H⋯O hydrogen bond consolidates the packing between cations and anions. International Union of Crystallography 2016-09-30 /pmc/articles/PMC5050784/ /pubmed/27746949 http://dx.doi.org/10.1107/S205698901601519X Text en © Pinto et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Pinto, Miguel Chakraborty, Indranil Mascharak, Pradip Synthesis and crystal structure of bis(1-{[(quinolin-8-yl)imino]methyl}pyrene-κ(2) N,N′)silver(I) trifluoromethanesulfonate |
title | Synthesis and crystal structure of bis(1-{[(quinolin-8-yl)imino]methyl}pyrene-κ(2)
N,N′)silver(I) trifluoromethanesulfonate |
title_full | Synthesis and crystal structure of bis(1-{[(quinolin-8-yl)imino]methyl}pyrene-κ(2)
N,N′)silver(I) trifluoromethanesulfonate |
title_fullStr | Synthesis and crystal structure of bis(1-{[(quinolin-8-yl)imino]methyl}pyrene-κ(2)
N,N′)silver(I) trifluoromethanesulfonate |
title_full_unstemmed | Synthesis and crystal structure of bis(1-{[(quinolin-8-yl)imino]methyl}pyrene-κ(2)
N,N′)silver(I) trifluoromethanesulfonate |
title_short | Synthesis and crystal structure of bis(1-{[(quinolin-8-yl)imino]methyl}pyrene-κ(2)
N,N′)silver(I) trifluoromethanesulfonate |
title_sort | synthesis and crystal structure of bis(1-{[(quinolin-8-yl)imino]methyl}pyrene-κ(2)
n,n′)silver(i) trifluoromethanesulfonate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5050784/ https://www.ncbi.nlm.nih.gov/pubmed/27746949 http://dx.doi.org/10.1107/S205698901601519X |
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