Stereoselective alkoxycarbonylation of unactivated C(sp(3))–H bonds with alkyl chloroformates via Pd(II)/Pd(IV) catalysis

Several examples on Pd-catalysed carbonylation of methyl C(sp(3))–H bonds with gaseous CO via Pd(II)/Pd(0) catalysis have been reported. However, methylene C(sp(3))–H carbonylation remains a great challenge, largely due to the lack of reactivity of C–H bonds and the difficulty in CO migratory insert...

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Detalles Bibliográficos
Autores principales: Liao, Gang, Yin, Xue-Song, Chen, Kai, Zhang, Qi, Zhang, Shuo-Qing, Shi, Bing-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5052708/
https://www.ncbi.nlm.nih.gov/pubmed/27678161
http://dx.doi.org/10.1038/ncomms12901

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