Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium‐Catalyzed Arylation

The synthesis of a new C (3v)‐symmetric crushed fullerene C(60)H(24) (5) has been accomplished in three steps from truxene through sixfold palladium‐catalyzed intramolecular arylation of a syn‐trialkylated truxene precursor. Laser irradiation of 5 induces cyclodehydrogenation processes that result i...

Descripción completa

Detalles Bibliográficos
Autores principales: Dorel, Ruth, de Mendoza, Paula, Calleja, Pilar, Pascual, Sergio, González‐Cantalapiedra, Esther, Cabello, Noemí, Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5053240/
https://www.ncbi.nlm.nih.gov/pubmed/27774038
http://dx.doi.org/10.1002/ejoc.201600311
Descripción
Sumario:The synthesis of a new C (3v)‐symmetric crushed fullerene C(60)H(24) (5) has been accomplished in three steps from truxene through sixfold palladium‐catalyzed intramolecular arylation of a syn‐trialkylated truxene precursor. Laser irradiation of 5 induces cyclodehydrogenation processes that result in the formation of C(60), as detected by LDI‐MS.

Ejemplares similares